AZ91D镁合金微弧氧化膜的致密性及其对耐蚀性的影响.pdfVIP

第25 卷第4 期 中国有色金属学报 2015 年4 月 Volume 25 Number 4 The Chinese Journal of Nonferrous Metals April 2015 文章编号：1004-0609(2015)04-0844-08 AZ91D 镁合金微弧氧化膜的 致密性及其对耐蚀性的影响 董海荣，马 颖，郭惠霞，张玉福，郝 远 (兰州理工大学 省部共建有色金属先进加工与再利用国家重点实验室，兰州 730050) 摘 要：在硅酸盐体系中对 AZ91D 镁合金进行微弧氧化处理，探讨膜层致密性的研究方法，推导膜层密度的计 算公式，定量分析膜层表面微孔的大小、分布及表面孔隙率随时间的变化，研究上述因素对膜层耐蚀性的影响。 结果表明：成膜物质基本不随时间的变化而发生改变，使膜层的致密性可以通过密度来间接研究；随着时间的延 长，膜层表面微孔逐渐变大，各微孔之间的大小差异及形状差异不断增大，膜层的表面孔隙率从8%逐渐增大到15% 。 处理时间为5 和10 min 时，膜层较致密，20 min 后，膜层的致密度明显减小，时间继续延长，致密度基本保持不 变。受膜层较大厚度、较高致密度、较少表面缺陷等多种优势共同存在的影响，30 min 时，试样的耐蚀性最好。 关键词：镁合金；微弧氧化；孔隙；致密性；耐蚀性 中图分类号：TG174 文献标志码：A Compactness of micro-arc oxidation coatings on AZ91D magnesium alloys and its effect on coating corrosion resistance DONG Hai-rong, MA Ying, GUO Hui-xia, ZHANG Yu-fu, HAO Yuan (State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China) Abstract: The coatings on AZ91D magnesium alloys were prepared by micro-arc oxidation (MAO) in silicate-containing electrolyte. The method to research the compactness of the coatings was discussed and a calculation formula of the density of the coatings was deduced. Meanwhile, the size and amount of the micro pores on the surface and the surface porosity of the coatings treated for different times were analyzed quantitatively. And the effect of the above factors on the corrosion resistance of the coatings was researched. The results show that, the phase composition of the coatings has no change wi