镓物理化学性调质研.pptVIP

镓 ;基本信息;物理化学特性;6063 Aluminum-Alloy →5 hours of corrosion under 120°C T2 Copper-Alloy Anodic Coloring 6063 Aluminum-Alloy 1Cr18Ni9 Stainless Steel;Morphology comparison of corroded surface of the 6063 Aluminum-Alloy (a) and of the T2 Copper-Alloy (b);EDS analysis;Conclusion;Anodic Coloring 6063 Aluminum→ It has very strong corrosion resistance. However, in the flowing liquid metal cooling system, the scouring effect that liquid metal of large density causes to the oxide layer on the surface must be considered.Meanwhile, the oxide layer cannot be scratched so as to avoid gallium infiltration. What is more, the system thermal resistance will increase because of the thin oxide layer. Thus, the Anodic Coloring 6063 Aluminum-Alloy can be used as structural material of a liquid metal cooling system only after certain good surface treatments. And the increased thermal resistance should be correctly evaluated for practical design of a liquid metal cooling system.;Corrosion resistance of structural materials to Ga2O at 1000 ℃;Conclusion;Compatibility of ITER Candidate Materials with Static Gallium;Conclusion;The Nb-5 Mo-l Zr alloy showed no measurable corrosion at 300 or 400°C；The Nb-5 Mo-1 Zr alloy showed no measurable corrosion at 300 or 4OOC, although there appeared to be significant attack of the cold-worked region. The surface of the specimens after exposure was smooth, with very little formation of inter-metallic compound An -0.5-mm-thick iron specimen reacted completely within 24 h（400℃）；Armco iron exposed to gallium at 300°C developed a very porous and thick reaction layer that was identified by X-ray diffraction (XRD) analysis as FeGa3, with gallium metal present in the pores. Similar corrosion behavior was observed for Nickel 270, in which the reaction layer primarily consisted of Ni2Ga3 and contained small amounts of NiGa4 in the region in contact