Fe3+Fe2+氧化还原电解液在高性能聚苯胺SnO2超级电容器中的应用.pdfVIP

Trans. Nonferrous Met. Soc. China 25(2015) 2661−2665 Fe3+/Fe2+ redox electrolyte for high-performance polyaniline/SnO supercapacitors 2 Tian-tian LIU, Yin-hai ZHU, En-hui LIU, Zhen-yu LUO, Tian-tian HU, Zeng-peng LI, Rui DING Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, China Received 9 October 2014; accepted 30 January 2015 Abstract: The Fe3+/Fe2+ redox electrolyte for use in polyaniline/tin oxide (PANI/SnO ) supercapacitors was reported. The influences 2 of redox electrolyte based on different Fe3+/Fe2+ ion pair concentrations in 1 mol/L H SO solution on the pseudocapacitive behaviors 2 4 of PANI/SnO2 supercapacitor were investigated. The electrochemical properties of the supercapacitor were studied by cyclic voltammetry (CV), galvanostatic charge−discharge (GCD), and electrochemical impedance spectroscopy (EIS) techniques. It is found that the performance of the supercapacitor is the best when the Fe3+/Fe2+ concentration is 0.4 mol/L and its initial specific capacitance is 1172 F/g at an applied current density of 1 A/g. The long-term cycling experiment shows good stability with the retention of initial capacitance values of 88% after 2000 galvanostatic cycles. The experimental results testify th