PTA醋酸甲酯水解过程厂级稳态模拟与集成优化.pdfVIP

2016 年 3 月 CIESC Journal March 2016 第 67 卷 第 3 期 化 工 学 报 Vol.67 No.3 PTA 醋酸甲酯水解过程厂级稳态模拟与集成优化 黄燕 1，薄翠梅 1，管国锋 2，丁帅 1 （1南京工业大学电气工程与控制科学学院，江苏 南京 211816；2南京工业大学化学化工学院，江苏 南京 211816） 摘要：针对 PTA 生产过程中副产物醋酸甲酯水解回收工艺，利用 Aspen Plus 软件进行厂级稳态流程模拟与集成优 化设计。首先分析水解工艺的热力学、动力学性质，建立水解工艺稳态流程模拟结构，与实际生产数据对比分析 验证稳态模拟结果的正确性；其次采用序贯优化法，以年生产成本最小化为目标，对工艺结构和操作参数进行优 化，使工艺达到最佳操作条件且生产成本最低。 关键词：醋酸甲酯水解；反应精馏；优化设计；稳态模拟 DOI：10.11949/j.issn.0438-1157 中图分类号：TQ 13 文献标志码：A 文章编号：0438—1157（2016）03—0912—07 Steady-state simulation and integrated optimization of reactive distillation for methyl acetate hydrolysis HUANG Yan1, BO Cuimei1, GUAN Guofeng2, DING Shuai1 (1College of Electrical Engineering and Control Science, Nanjing Tech University, Nanjing 211816, Jiangsu, China; 2College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu, China) Abstract: For recovery process of methyl acetate hydrolysis, this paper simulated process and designed integrated optimization by using Aspen Plus software. Firstly, analyses of thermodynamic and kinetic properties of the hydrolysis process were given. Secondly, the paper established steady-state process simulation structure of hydrolysis process and verified the accuracy of steady-state results. Then it used sequential optimization method to optimize process structure and operation parameters at the aim of achieving minimum production cost. The results showed that operating condition was the best and production cost was the lowest after optimization. Key words: hydrolysis of methyl acetate; reactive distillation; optimization design; steady-state simulation 引 言 在精对苯二甲酸（PTA）生产中，醋酸发生不 完全氧化反应生成副产物醋酸甲酯，造成醋酸的损 耗，导致 PTA 生产成本较高。将醋酸甲酯水解为醋 酸和甲醇既可以实现资源再利用，又可以减少环境 污染[1]。近年来，国内展开了对醋酸甲酯水解催化 精馏技术的开发与研究，邱挺等[2]进行醋酸甲酯反 应精馏研究，水解率提高的同时能耗降低 40%。王 良恩等[3]将醋酸甲酯水解专