SCR烟气脱硝对PM2.5排放特性的影响机制研究.pdfVIP

文章编号: 0253-2409(2015)12-1510-06 Received: 2015-06-02; Revised: 2015-08-27. *Corresponding author. E-mail: ylj@ seu. edu. cn. The project was supported by the Major State Basic Research Development Program of China (973 program, 2013CB228505) and the Science and Technology Project of Electric Power Research Institute of Guangdong Power Grid Company (K-GD2013-055) . 国家重点基础研究发展规划 (973 计划, 2013CB228505)和广东电网有限责任公司科技项目(K-GD2013-055)资助项目 SCR烟气脱硝对 PM2. 5 排放特性的影响机制研究 束 航1, 张玉华1, 杨林军1,*, 刘亚明2, 李方勇2, 徐齐胜2, 盘思伟2 (1.东南大学能源热转换及其过程测控教育部重点实验室,江苏 南京 210096; 2.广东电网有限责任公司电力科学研究院,广东 广州 510080) 摘 要: 采用 V2O5 -WO3 / TiO2 催化剂,对选择性催化还原(SCR)烟气脱硝装置出口 PM2. 5物性进行分析,考察 SO2 氧化与 PM2. 5形成的关系,并采用原位漫反射红外光谱(DRIFTS)对 SCR 脱硝过程中 NH4HSO4 的生成及 SCR 脱硝温度条件下的 NH4HSO4 热稳定性进行了分析研究。 结果表明,经 SCR脱硝后,亚微米级细颗粒数浓度明显升高,且形貌特征及元素组成发 生变化,形成的细颗粒主要为 NH4HSO4 及少量(NH4) 2SO4;SCR烟气脱硝对 PM2. 5排放特性的影响主要通过以下途径:一是 SO3 与 SCR烟气脱硝系统中的 NH3、H2O反应形成;二是 SO3 与逃逸的 NH3、H2O在 SCR脱硝装置后续系统发生反应形成硫 酸氢铵与硫酸铵;此外还与 SO3 和烟气中游离的 CaO等碱土金属氧化物反应形成硫酸盐,随烟气携带出 SCR脱硝装置有关。 关键词: 细颗粒物; SCR脱硝; 排放特性; 影响机制 中图分类号: X511 文献标识码: A Effects of SCR-DeNOx system on emission characteristics of fine particles SHU Hang1, ZHANG Yu-hua1, YANG Lin-jun1,*, LIU Ya-ming2, LI Fang-yong2, XU Qi-sheng2, PAN Si-wei2 (1. Southeast University, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Nanjing 210096, China; 2. Electric Power Research Institute of Guangdong Power Grid Company, Guangzhou 510080, China) Abstract: Based on V2O5 -WO3 / TiO2 catalyst, the size distribution, morphology, element compositions and chemical compositions of fine particles at the output of SCR-DeNOx system were analyzed, and the formation mechanism of fine particles were discussed based on DRIFTS systematically. The results show that great quantities of particles can be formed during the process of SCR-DeNOx . The main components of particles are ammonium bisulfate and a small amount of ammonium sulfate. The effects of SCR-DeNOx system on emission characteristics of fine parti