NTA翻译教程.doc

Chemical cleaning (nta-procedure) of acfb-boilers suzhou 苏州ACFB-锅炉化学清洗（NTA程序） 1 Boil out NTA氮川三乙酸煮炉 General综述 This document includes a general description for chemical cleaning of the evaporator system by using “Nitrilo-tri- acetic- acid”(NTA). 本文档描述使用 “氮川三乙酸”(NTA)对蒸发系统进行化学清洗。 Reference drawing:参考图纸 K170040.B.101.007 PI diagram流程图 Boiler design data:锅炉设计数据 Maximum rating 最大功率 275 t/h Maximum continuous rating最大持续功率 250 t/h Operation pressure操作压力 P=125 bar(a) Operation temperature 操作温度 T=540 ℃ Feedwater temperature(after feedwater tank) T=156℃ 给水温度（除氧器后） Feedwater temperature(after hp-preheater) T=200℃ 给水温度（高加后） Chemistry化学 The principle of the internal chemical cleaning is the removal of oxide layers, scale and other deposits, in order to create a metallic clean surface, upon which a homogeneous magnetite layer can be formed. 内部化学清洗是为去除氧化层, 剥落层和其他沉积物,达到一个金属清洁表面,这就可以形成一层均匀的磁铁矿层。 On the other hand it is necessary to get the required steam quality for turbine operation as fast as possible.另一个方面，有必要尽可能快地获得汽机操作所需的蒸汽质量。 Nitrilo-tri-acetic-acid(NTA) is an organic chelating agent and removes deposits containing iron oxides (Fe304) under alkaline (nh3) and reducing (n2h4) conditions at temperatures between 160-220℃. 氮川三乙酸(NTA)是一种有机络合剂并能除去碱性(NH3)下的含铁氧化物(Fe304)的沉积物以及在条件温度160 - 220℃之间还原(N2H4)。 Temperatures 220℃ effecting a partly decomposition of the chelating chemical. 温度 220℃影响螯合化学物质的部分分解。 Hooc-ch2 \ N-ch2-coonh4 / Hooc-ch2 Alkaline conditions are to be achieved by using the mono ammonium salt of nta.(the reaction with pure iron surface is very low) 使用NTA的单铵盐达到碱性条件。（用纯铁表面上的反应是非常低的） Reducing conditions will be achieved by using of hydrazine (n2h4) 还原条件将通过使用肼来实现（N 2 H 4） Fe3O4(FeOFe2O3)+1/2n2h4 3FeO+1/2N2+h2o Nh4nta reacts with fe2 +ions of the oxide and forming a stable 1:1 complex with NTA Nh4nta与Fe2+的氧化物离子反应形成稳定的1：1 NTA复合物 FeO +ntanh4 ntafe +nh4o