比表面积和灰分对烟煤半焦气化机理的影响.pdfVIP

第 35 卷 第 20 期 中 国 电 机 工 程 学 报 Vol.35 No.20 Oct. 20, 2015 5244 2015 年 10 月 20 日 Proceedings of the CSEE ©2015 Chin.Soc.for Elec.Eng. DOI：10.13334/j.0258-8013.pcsee.2015.20.015 文章编号：0258-8013 (2015) 20-5244-07 中图分类号：TQ 511；TQ 54 比表面积和灰分对烟煤半焦气化机理的影响 唐佳，王勤辉，张睿，施正伦，岑可法 (能源清洁利用国家重点实验室(浙江大学)，浙江省 杭州市 310027) Effect of Specific Surface Area and Ash Content on the Mechanisms of Bituminous Coal Char Gasification TANG Jia, WANG Qinhui, ZHANG Rui, SHI Zhenglun, CEN Kefa (State Key Laboratory of Clean Energy Utilization(Zhejiang University), Hangzhou 310027, Zhejiang Province, China) ABSTRACT: Two different controversial assumptions, common or separate active sites assumptions, existed in the Langmuir-Hinshelwood (L-H) kinetic model when coal char gasified by the mixture of H2O and CO2. This paper proposed two potential factors, specific surface area and ash content, to elucidate the reason for this controversial issue. Experiments were conducted at atmospheric condition and a temperature of 1223K, using a modified thermogravimetric analyzer (TGA) system at various reactant partial pressures. The experimental results showed that both specific surface area and ash content will affect the mechanisms of coal char gasification. The experimental data of coal char with large specific surface area fit the calculation of separate active sites assumption, while the experimental data of coal char with small specific surface area fit the calculation of another assumption very well. The experimental data of demineralized char didn’t fit the calculation which based on both of these two active sites assumptions. KEY WORDS: coal char gasification; gasification kinetics; specific surface area; ash content 摘要：Langmuir-Hinshelwood (L-H) 动力学模型在描述 H2O 与 CO2 混合气氛下的煤焦气化时，存在公共活性位与单独 活性位 2 种矛盾的反应机理假设。为解释这一矛盾现象，提 出了比表面积和灰分 2 种可能的因素。实验在改造后的热重 分析仪上进行，实验系统压力为常压，反应温度为 1223K。 实验结果表明，比表面积和灰分均会对煤焦气化机理产生影 响。比表面积较大的煤焦，其实验结果更符合基于单独活性 位假设的 L-H 模型预测值，而比表面积较小的煤焦，其实 验结