月桂酸键合改性氢氧化镁的制备及其在聚乙烯中的应用.PDF

第3卷 第6期 中国科技论文在线 SCIENCEPAPER ONLINE 2008 年 6 月 415 月桂酸键合改性氢氧化镁的制备及其 在聚乙烯中的应用 庞洪昌，叶俊伟，李俊强，颜 峰，林 源，宁桂玲 （大连理工大学化工学院材料化工系, 辽宁省微纳米技术重点实验室，辽宁大连 116012） 摘 要：微米级氢氧化镁是一种应用于高分子材料的无毒环保型阻燃剂。但是由于其表面的强极性而致使其与 高分子材料之间相容性较差。为了改善它们之间的相容性，本文探索研究一种使氢氧化镁与月桂酸反应生成 Mg-O-C化学键的包覆改性微米氢氧化镁的方法；并且通过红外光谱等表征手段证明月桂酸键合到了氢氧化镁 表面。初步研究改性后的氢氧化镁在聚乙烯中的加工及力学性能。 关键词：无机化学工程；阻燃剂；月桂酸；氢氧化镁；改性 中图分类号：O614.22; O647.11 文献标识码：A 文章编号：1673－7180(2008)06－0415－4 Study of modification of magnesium hydroxide bonded with lauric acid and application in PE PANG Hongchang，YE Junwei，LI Junqiang，YAN Feng，LIN Yuan，NING Guiling (State Key Laboratory of Fine Chemicals; Key Laboratory for Micronano Technology and System of Liaoning Province; Dalian University of Technology; Dalian, liaoning 116012) Abstract: Magnesium hydroxide (Mg(OH) 2) microparticles are nontoxic and can be prepared as a flame retardant for polymer, but they do not have good compatibility in polymer materials because of their high polarity. In order to improve their compatibility, Mg(OH)2 microparticles readily react with lauric acid to give C-O-Mg bond. The synthesis process of a novel Mg(OH) 2- lauric acid microparticle is described. The modified magnesium hydroxide is characterized by FT IR to prove that lauric acid is bonded to Mg(OH) 2 surface. Mg(OH) 2 treated with lauric acid take a good performance in polyethylene (PE).