纳米二氧化硅及载银抗菌剂制备与表征.PDFVIP

第 3 卷 第 1 期 包 装 学 报 Vol.3 No.1 2011 年 1 月 Packaging Journal Jan. 2011 纳米二氧化硅及载银抗菌剂制备与表征 庹 度 （湖南工业大学 专业设计中心，湖南株洲 412008） 摘 要：在不同的醇溶剂环境中，采用水解法制备了粒径大小不同的纳 微米二氧化硅（ ），研究了不 / SiO2 同醇溶剂对 粒子大小的影响。实验结果表明，随着醇溶剂分子量的增大， 的粒径逐步增大。通过浸渍 SiO2 SiO2 吸附和化学还原两步法成功制备了 载银抗菌剂，并优化了制备工艺条件。抑菌实验检测显示，二氧化硅载 SiO2 银（ ）抗菌剂对金黄色葡萄球菌和大肠杆菌的抑菌圈大小分别为 和 。 SiO2/Ag 15.3 mm 10.4 mm 关键词：二氧化硅；载银；复合纳米粒子；抗菌剂 中图分类号：TQ127.2；TB333 文献标志码：A 文章编号：1674-7100(2011)01-0048-05 Preparation and Characterization of Silver Loaded Nanosilica Antibacterial Agent Tuo Du （Packaging Engineering Design Centre, Hunan University of Technology, Zhuzhou Hunan 412008, China） Abstract ：The conventional Stober method is used to prepare silica microsphere in different alcohol solutions. The influence of different alcohol solvent on the size of silica is discussed. The results indicate that the diameter of silica is gradually increased with the molecular weight of methanol, ethanol, propyl alcohol and buthanol and the mechanism is also discussed subsequently. Taking the silica prepared as a carrier, SiO2/Ag composites by adsorption and chemical reduction are obtained. The SiO2/Ag composites are very sensitive to golden brown staphylococcus and Escherichia coli with the inhibition zone diameter of 15.3 mm and 10.4 mm respectively. Key words：silica(silicon dioxi