carbene mediated reactions.pptVIP

陈 应 春 Tel:Email: ycchenhuaxi@ 药学大楼906室;Internet 上的国际化学资源;德国化学会网址: ;英国化学会网址：;Elsevier出版社网址：;SynlettSynthesisSynfactsSynform;有机合成系列丛书： (free) ;Nucleophilic Carbene catalyzed Reactions;Enzymes Set the Standards;Benzoin Condensation Catalyzed by in situ Formed Carbene;The First Crystalline Carbene;Isolable Analogues of the Breslow Intermediate;Various Carbene Structures;Carbene as Versatile Ligand for Transitional Metal Complex;Umpolung Reactions Catalyzed by Organic Nucleophilic Carbene;Asymmetric Benzoin Reactions;Ender et al. Angew. Chem. Int. Ed. 2002, 41, 1743.;Reaction with Acylimine Acceptors;Asymmetric Catalysis ;Catalytic Mechanism;Asymmetric Stetter Reaction;Intermolecular Stetter Reactions;Scheidt et al, J. Am. Chem. Soc. 2005, 127, 4932.;First Asymmetric Intramolecular Stetter Reactions by Enders;Rovis et al. JACS, 2002, 124, 10298.;Rovis et al. Synlett, 2003, 1934.;Rovis et al. JACS, 2005, 127, 6284.;Asymmetric Synthesis of Hydrobenzofuranones;Hydroacylation of Cyclopropenes;Glorius, F. et al. JACS, 2011;Conversion of ?-Haloaldehydes into Acylating Agents; Rovis et al. JACS, 2004, 126, 9518.;Synthesis of Chiral ?-Chloroesters; Rovis et al. JACS, 2005, 127, 16406.;Carbene-Catalyzed Generation of Homoenolates;Postulated Catalytic Cycle for Lactone Formation;Catalytic Synthesis of Lactams;Bode et al. Org. Lett. 2005, 7, 3131;Annulation reaction of isatin N-Boc ketimines and enals;Efficient Synthesis of 1,3,4-Trisubstituted Cyclopentenes;Postulated Catalytic Cycle Involving NHC;Cooperative N-Heterocyclic Carbene/Lewis Acid Catalysis;Scheidt et al, JACS. 2010.;Generation of Activated Carboxylates from Enals;Bode, Org. Lett. 2005, 7, 3873;LUMOdiene-controlled Azadiene Diels-Alder Reactions;Bode et al. J. Am. Chem. Soc. 2006, 128, 8418.;Oxodiene Diels-Alder Reactions;Asymmetric Synthesis of Highly Substituted b-Lactones;Scheidt et al, ACIE. 2012, early view.;Redox Esterifications of ChiralFormylcyclopropanes;Bode et al. Angew. Chem. Int.