柠檬酸酯合成用催化剂研究进展汇.docVIP

柠檬酸酯的合成及研究 摘要 介绍了近年来柠檬酸酯类化合物的合成方法及主要用途。对各类催化剂，如磺酸类、固体超强酸、杂多酸、无机盐等在合成柠檬酸酯上的应用进行了综述，并分析比较了各种催化剂的优缺点。介绍了固栽交联、纳米、磁化、微波辐射等技术在催化剂改性上的应用，展望了柠檬酸酯合成的发展前景。 Abstract：Using H2 SO4，P-toluene sulphonic acid and NaHSO4 as the catalysts，the catalytic synthesisprocesses of tributyl citrate were investigated．Then three compounds were loaded on the active carbon andthe influence on homogeneous and heterogeneous system was studied．The results showed that the activecarbon—supported catalysts exhibited good catalytic activity，and C-H2SO4 was determ ined as the most suitablecatalyst for the synthesis of tributyl ci