锂电池高温存放后的电化学容量衰减.pdfVIP

Journal of The Electrochemical Society, 152 ?6? A1041-A1046 ?2005? A1041 0013-4651/2005/152?6?/A1041/6/$7.00 ? The Electrochemical Society, Inc. Electrochemical Investigations on Capacity Fading of Advanced Lithium-Ion Batteries after Storing at Elevated Temperature Mao-Sung Wu,*,z Pin-Chi Julia Chiang, and Jung-Cheng Lin Industrial Technology Research Institute, Materials Research Laboratories, Hsinchu 310, Taiwan Capacity fading of advanced lithium-ion batteries after elevated temperature storage was investigated by three-electrode measure- ments. Capacity fading of a battery increases by increasing the state-of-charge ?SOC? during storage, especially at elevated temperatures. The reversible capacity of a battery ?SOC = 100%? at 60°C decreases from 820 to 650 mAh ?79.3% capacity retention? after 60 days. At room temperature, a battery SOC in?uences the capacity fading only slightly; after 65 days of storage, the reversible capacity decreases from 820 to 805 mAh ?98.2% capacity retention?. Individual effects by the anode, cathode, and electrolyte on capacity fading are analyzed with three-electrode electrochemical ac impedance. The major contribution, from X-ray photoelectron spectroscopy ?XPS? and energy-dispersive spectroscopy results, comes from cathode degradation as a result of cobalt dissolution at the LiCoO2 surface layer. A minor contribution comes from the continuous reactions between lithiated mesocarbon microbead ?MCMB? electrode and electrolyte components, which in turn thicken the SEI ?lm and consume available lithium ions. From X-ray diffraction and XPS results, high-temperature storage in?uences only the surface properties of MCMB