马铃薯淀粉基炭微球的制备及其稳定机理_英文_.pdfVIP

第 25卷 第 6期 新 型 炭 材 料 V o.l 25 N o. 6 2010年 12月 N EW CARBON MAT ER IAL S Dec. 2010 Artic le ID: 10078827( 2010) 06043806 Preparation of carbon spheres from potato starch and its stabilization mechanism ZHAO Shuo, W ANG Chengyang, CHEN M ingm ing, SH I Zhiqiang, L IU N a (K ey Labora tory for Green Chem ica lT echnology of S ta teEd uca tion M inistry, S chool of Chem ica lE ng ineering and T echnology, Tianjin Un iversity, T ianjin 300072, Ch ina ) Abstrac t: C arbon spheres pe rfectly re ta in ing the o rig ina l m o rpho lo gy o f po ta to starch w e re prepared by a tw ostep pro cess includ ing stabiliza tion and ca rbo nization. The po ta to sta rch w as f irst stab ilized a t 210 under a ir, and the stab i lized sam p le s w ere then carbon ized a t 600 fo r 1h underN 2 a tm o sphere. In the pro cess, stab ilizatio n trea tm ent w a s the m a in step. T he m echanism o f stab iliza tion w as inv estiga ted by therm o grav im etric ana ly sis, X ray d iffraction, X ray pho toe lec tron spectro scopy, and d ifferen tia l scanning calo rim e try, and the m o rpho log y o f the carbon spheres w a s cha rac te r ized by scann ing e lec tro n m icro scopy ( SEM ). R esults show that during stabiliza tion, the lo ss o f w ater and the occur rence of decom po sition and condensatio n reaction s re su lt in the destruction o f the cry sta llite structure in the o rig ina l po tato starch. T hus, during the carbon izatio n step, further in term o lecular cro sslink ing m ake sm icro cry sta lline m e lting ve ry d if ficu lt. T h is prom o tes the fo rm a tion o f m onodispersed carbon sphere s. T he