固体聚离子液体的有序性表征教程.ppt

聚离子液体有序性表征;;离子液体（IL）：是指由有机阳离子和无机阴离子组成的物质,一般认为其熔点低于100℃。 聚离子液体(PIL)即是离子液体的聚合物，与离子液体相比最大的优点就是空间可控性。;;2：聚离子液体自组装;所以我们有必要通过合适的表征手段对两亲性聚离子液体自组装后的局部有序性行为进行研究而且通过结构有序性的研究可以与聚离子液体的一些性质进行关联。;直接 cryo-TEM X-ray diffraction Differential scanning calorimetry Polarized optical microscopy (POM) AFM 间接 6. small angle X-ray scattering (SAXS);dispersion polymerization：The polymerization proceeded over 24 h at a monomer concent ration of 50 g/L in aqueous solutions at 70℃ using the water-soluble nonionic initiator 2,2-azobis[2-methyl-N-(2-hdroxyethyl) propionamide] (VA86).;用冷沉淀-TEM;DSC;5.Influence of Anion Exchange in Self-Assembling of Polymeric Ionic Liquid Block Copolymers Pedro Maria Carrasco,Alaitz Ruiz de Luzuriaga,Marios Constantinou,Prokopios Georgopanos,SofiaRangou,Apostolos Avgeropoulos,Nikolaos E. Zafeirop oulos,Hans-Jurge Gran de,German Caba~nero,David Mecerreyes,and Ignacio Garcia* ;small angle X-ray scattering (SAXS);常见的溶致液晶种类;d;lyotropic Hexagonal liquid crystal;普适性规律;0.195，0.339，0.394，满足 2D六方柱状结构;3D Interconnected Ionic Nano-Channels Formed in Polymer Films: Self-Organization and Polymerization of Thermotropic Bicontinuous Cubic Liquid Crystals;The Effect of Cation Structure on the Mesophase Architecture of Self-Assembled and Polymerized Imidazolium-Based Ionic Liquids Dolly Batra, So¨nke Seifert, Millicent A. Firestone*;总结;谢谢