O2CO2气氛添加高岭石对PM25排放影响.pdfVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：094139 O2/CO2 气氛添加高岭石对 PM2.5 排放影响 屈成锐 赵长遂 段伦博 周骛 （东南大学热能工程研究所，南京 210096） (Tel: +86 25 Email: cszhao@seu.edu.cn) 摘 要：采用管式炉研究了添加高岭石对PM2.5 (空气动力学直径小于2.5μm的颗粒物)排放特性的影 响。燃烧试验在1123K，O2/CO2气氛下进行。试验采用荷电低压撞击器(ELPI)采集燃烧后的PM2.5。结 果显示添加高岭石是燃烧过程中影响PM2.5生成的重要因素。添加高岭石后，生成PM1的数量和质量浓 度均降低，而PM1-2.5的数量和质量浓度均增加；PM2.5粒径分布都是相似的双峰分布，峰值点分别出现 在0.2μm和2.0μm左右。随着高岭石添加量的增加，PM2.5中的S、Pb、Cu、Na和K几种元素的浓度值呈 下降趋势。粒径小于0.317μm的颗粒可能通过气化-凝结机理形成，而超微米颗粒则可能是通过亚微米 颗粒凝聚、聚结和矿物质熔融、破碎、聚结形成。 关键词：O2/CO2；燃烧；PM2.5；形成机理；添加剂 中图分类号：TK16 文献标识码：A 学科分类号：470·40 EFFECT OF KAOLINITE ADDITIVE ON EMISSION OF PM2.5 IN O2/CO2 ATMOSPHERE QU Cheng-rui ZHAO Chang-sui DUAN Lun-bo ZHOU Wu (Thermoenergy Engineering Research Institute, Southeast University, Nanjing 210096, China) Abstract: The influence of kaolinite additive on the emission characteristics of PM2.5 (particulates with diameters less than 2.5μm) has been studied with a tube furnace. The combustion tests were carried out at 1123K under O2/CO2 conditions. The PM2.5 generated from coal combustion was collected into an Electrical Low Pressure Impactor (ELPI). Results indicate that kaolinite is an important factor for the formation of PM2.5 during coal combustion. The number and mass concentration of PM1 diminished, but the number and mass concentration of PM1-2.5 enhanced after kaolinite was added. The size distributions of PM2.5 were similar, which displayed two peaks around 0.2μm and 2.0μm, respectively. With increasing of additive amount of kaolinite, the concentrations of S, Pb, Cu, Na and K decrease. The ash particles smaller than 0.317μm were for