CatalyzedbySodiumMethoxide.PDF

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CatalyzedbySodiumMethoxide.PDF

Journal of Natural Gas Chemistry 13(2004)225–230 Kinetics of Methanol Carbonylation to Methyl Formate Catalyzed by Sodium Methoxide Liang Chen1?, Jianghong Zhang2, Ping Ning1, Yunhua Chen1, Wenbing Wu1 1. Research Center of C1 Chemical Technology, Kunming University of Science and Technology, Kunming 650093, China 2. College of Science, Kunming University of Science and Technology, Kunming, 650093, China [Manuscript received August 23, 2004; revised November 15, 2004] Abstract: Kinetics of synthesis of methyl formate from carbon monoxide and methanol, using sodium methoxide as the catalyst and pyridine as the promoter in a batch reactor, was studied. Kinetic parameters such as the apparent reaction orders, the rate constant and the apparent activation energies were obtained. The experimental results showed that both the reaction orders with respect to CO and methanol equal to 1, the general reaction kinetic equation is (?r)=–dp(CO)/dt=k · p(CO)·[MeOH], and the rate constant is k=8.82×106 exp [–61.19×103 /(R · T )] in the presence of pyridine. The apparent activation energies had decreased 6.44 kJ/mol and the rate constant had increased more than 1.5 times when pyridine was used as the promoter in the catalyst system. Key words: carbon monoxide, pyridine, methanol, methyl formate, carbonylation, kinetics 1. Introduction cial production of methyl formate via carbonyla- tion of methanol and catalyzed by sodium methoxide (CH3ONa) is effective in quite large scales [20]. Methyl formate (HCOOCH3) is an important and However, carbon monoxide (CO) obtained from versatile chemical inte

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