2008讲稿-第6章.pptVIP

Chapter 6. Surface Tension and Contact Angle;Focus of this Chapter;6.2 Surface tension, surface work and surface free energy;γ=F/2L (1);（1） Reason for producing surface tension;Based on kinetic molecular theory of gases(气体分子动力学理论) and theory of diffusion in liquids(液体扩散理论), when temperature is in 20?C： Exchange rate of molecules between surface and vapor is: 2.9×1020 / s.cm2 Exchange rate of molecules between surface and liquid is: 1.7×1025/s.cm2;In equilibrium the distance between the molecules on the surface is larger than that in liquid, there is “vacant position” on the