3微波-Fenton氧化-絮凝法处理含油废水机理分析-环境工程学报.doc

微波-Fenton氧化-PAFSi絮凝法处理含油废水 的实验研究 施国飞1作者简介：施国飞（1987~），男，云南楚雄人，昆明理工大学2010级硕士研究生，研究方向为水污染控制新技术，E-mail:237884259@ 徐晓军2 通讯作者：徐晓军，教授/博导；电话-mail:xuxiaojun88@ 贾佳3 郑鑫1 管堂珍1 陈晓鸿1 (1,2. 昆明理工大学环境科学与工程学院, 昆明, 650500, 中国; 3. 浙江环科环境咨询有限公司, 杭州, 310007, 中国) [摘要] 实验采用微波-Fenton氧化-PAFSi絮凝法处理含油废水。结果表明：200mL水样先经微波辐射6min，在pH=2，H2O2 (30%)3.5g/L，Fe2+ 1.3g/L的条件下氧化4小时后，采用聚硅酸铝铁（Al:Fe:Si=10:2:1）和聚丙烯酰胺在pH=8时进行絮凝实验，处理后废水浊度、SS、COD、含油量、色度分别降低了99.46%、96.66%、91.94%、97.97%、95.00%，且经处理后废水的BOD/COD由原水的0.04提高到0.53。实验还分析了含油废水的降解机理。 [关键字] 含油废水；絮凝；Fenton氧化；微波 [文章编号] 1000-8144（2012）-0000-00 [中图分类号] [TQ09] [文献标识码] A Experiment research on the treatment of oily wastewater by microwave - Fenton oxidation – PAFSi flocculation Shi Guofei1 Xu Xiaojun2 Jia Jia3 Zheng xin1 Guan Tangzhen1 Chen Xiaohong1 (1, 2.Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China; 3. Zhejiang Environmental Sciences Limited Company of Environmental Consulting, Hangzhou 310007, China) [Abstract] The microwave-Fenton oxidation-flocculation method was investigated to treat the oily wastewater. In this study, 200 mL of wastewater was treated with microwave for 6 min, then oxidated 4 hours in the condition of pH=2, 3.5g/L of H2O2 (30%), 1.3 g/L of Fe2 +. Final poly aluminum silicate iron (Fe:Al:Si = 10:2:1) and polyacrylamide were used in the flocculation experiment (pH=8). The results showed that the turbidity, SS, COD, oil content and chrominance of effluent decreased by 99.46%, 96.66%, 91.94%, 97.97% and 95.00%, the value of BOD/COD changed from 0.04 to 0.53 after treatment, which indicated the water quality had been improved greatly, and the treatment effect was remarkable. The degradation mechanisms of oily wastewater were also analysed. [Key words] waste water containing oil; flocculate; Fentons oxidant; microwave 含油废水主要是指来源于含油工业企业排放的难降解有机废水，含油污水水质复杂，其中所含的多种污染物对水体水质会造成很大的危害[1]。目前国内外对含油废水的处理流程大多为：废水破乳后再采用重力分离、气浮、吸附、膜过滤和生物