α-Fe2O3纳米材料的固相合成及光催化降解亚甲基蓝性能.pdf

Hans Journal of Nanotechnology 纳米技术, 2016, 6(1), 14-21 Published Online February 2016 in Hans. /journal/nat /10.12677/nat.2016.61003 文章引用: 王碧军, 刘劲松, 李子全, 黄洁文, 李云朋, 丛孟启, 冯冰, 陈建康, 朱孔军, 裘进浩. α-Fe2O3 纳米材料的 固相合成及光催化降解亚甲基蓝性能[J]. 纳米技术, 2016, 6(1): 14-21. /10.12677/nat.2016.61003 Solid-State Synthesis of α-Fe2O3 Nanomaterials and Photocatalytic Degradation Performance on Methylene Blue Bijun Wang1, Jinsong Liu1*, Ziquan Li1, Jiewen Huang1, Yunpeng Li2, Mengqi Cong1, Bing Feng1, Jiankang Chen1, Kongjun Zhu3, Jinhao Qiu3 1College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing Jiangsu 2Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou Fujian 3State Key Laboratory of Mechanics and Control of Mechanical Structures, Nanjing University of Aeronautics and Astronautics, Nanjing Jiangsu Received: Feb. 2nd, 2016; accepted: Feb. 20th, 2016; published: Feb. 23rd, 2016 Copyright © 2016 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract Precursors were synthesized by a solid-state synthesis method. And α-Fe2O3 nanomaterials were obtained by thermal decomposition of precursors at different calcination temperatures. The crys- tal structure, microstructure morphology and optical properties of the α-Fe2O3 nanoparticles were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, Field scanning electron microscopy (FESEM), and UV-vis diffuse reflectance spectroscopy (DRS). The results show that the energy gap and particle size of the α-Fe2O3 nanomaterials increase with an- nealing temperature. But they are all less than bulk α-Fe2O3 (2.2 eV). The α-Fe2O3 nanoparticles prepared at 500˚C for 2 h exhibit the highest visible-light photocatalytic efficiency of 70.60% and photodegradation rate constant, k, of 6.78 × 10−3