Glucosamine with three kinds of copper-cobalt-nickel-metal ion coordination properties of.docVIP

 PAGE \* MERGEFORMAT 7 Glucosamine with three kinds of copper-cobalt-nickel-metal ion coordination properties of Authors: Dong Li, Su-Ying Ma, Yang Li-min, SUN Xiang-de [Abstract] Objective To study the protonated glucosamine and with Cu2, Co2, Ni2 of the coordination properties. Methods The pH potentiometric titration (298 ± 0.1) K, I = 0.10 mol/LKNO3 glucosamine under the conditions of the protonation constants and with Cu2, Co2, Ni2 binary complex formation constants. Results glucosamine pKa of 7.78, the complex logarithm is generated constants were: Cu2, 5.22 (110), 9.38 (120); Co2, 3.19 (110), 5.99 (120); Ni2, 3.40 (110), 6.31 ( 120). Conclusions Glucosamine with Cu2, Co2, Ni2 coordination from the time puzzling out the alcohol hydroxyl protons, the different constants of metal ion complexes generated in line with the size of the Irving-William sequence. [Keywords:] glucosamine complex generates constant Abstract: Objective To study the coordination reaction of glucosamine with Cu2, Co2 and Ni2. MethodsThe protonation of glucosamine and complex formation constant of glucosamine with Cu2, Co2 and Ni2 binary complexes were determined at 298K, I = 0.1 mol / L KNO3 by pH method . ResultsThe protonation of glucosamine was pKa7.78. The formation constants were Cu2, 5.22 (110), 9.38 (120); Co2, 3.19 (110), 5.99 (120); Ni2, 3.40 (110), 6.31 (120). ConclusionProton of alcoholic hydroxyl does not dissociate when coordinated to Cu2, Co2 and Ni2. The stability of binary complexes accord with the Irving-William order of meta1 ions for the same ligand. Keywords:: Glucosamine; Complex; Formation constant Chitin, also known as chitin, chitin, chitosan, etc., is a widely found in crustaceans such as crabs, shrimp, mollusks, insects and higher plant cell walls in a linear amino polysaccharide, its rich resources, is a natural In addition to the largest number of nitrogen-containing proteins outside the natural organic polymer, is widely used in industry, agriculture,