1材料与方法-环境工程学报.doc

拟再审修改稿 稿件编号： 201301070 共沉淀法制备铁锌基中高温煤气脱硫剂的研究 孙振丽123，杨新芳23，田文栋23，赵丽凤23，肖云汉23 （1.中国科学院大学，北京 100049；2.中国科学院先进能源动力重点实验室（工程热物理研究所），北京 100190；3.中国科学院能源动力研究中心，江苏省连云港市 222069） 摘要：采用共沉淀法制备Cu-Zn-Fe脱硫剂，优化共沉淀制备工艺。固定床实验结果表明共沉淀溶液中金属离子总浓度为0.6 mol/L，焙烧温度600oC，添加10%活性助剂Cu时所得Cu-Zn-Fe脱硫剂循环脱硫性能最佳，此时ZFDCu10脱硫剂的硫容可达到41.2 g S / 100 g脱硫剂。XRD和SEM对铁锌基脱硫剂的表征结果表明加入Cu助剂后少量的ZnO、CuO可阻碍ZnFe2O4晶粒聚集，增强铁锌基脱硫剂活性组分的分散性，避免大晶粒的ZnFe2O4硫化时形成较多的产物层而降低脱硫剂的利用率。实验结果为制备脱硫性能较好的Cu-Zn-Fe脱硫剂提供了理论依据。 关键词：铁锌基 共沉淀 高温煤气 脱硫 中图分类号 X511 文献标识码 A 文章编号 Preparation of zinc ferrite-based sorbent using coprecipitation method for medium-high temperature coal gas desulfurization Sun Zhenli123, Yang Xinfang23, Tian Wendong23, Zhao Lifeng23, Xiao Yunhan23 (1. University of Chinese Academy of Sciences, Beijing 100049, China; 2. Key Laboratory of Advanced Energy and Power, Chinese Academy of Sciences (Institute of Engineering Thermophysics), Beijing 100190, China; 3. Research Center for Clean Energy and Power, Chinese Academy of Sciences, Lianyungang, Jiangsu Province, 222069, China) Abstract Cu-Zn-Fe regenerable sorbents were prepared and optimized by coprecipitaion method. The performance of sorbents was tested using a fixed-bed reactor, and the results indicated that the sorbent exhibited a high sulfur capacity of 41.2 g S / 100 g sorbent at one condition which the total metal ion concentration was 0.6 mol/L, the calcination temperature was 600oC, and the additive was 10% Cu. The results of XRD and SEM showed that the assistance Cu could prevent the aggregation of ZnFe2O4 crystals with the presence of a little ZnO and CuO, improve the dispersion of the active ZnFe2O4 component, and avoid the formation of more product layers which would result the lower utilization of the desulfurizer. The experimental results provide a theoretical basis for the preparation of Cu-Zn-Fe sorbents with good desulfurization performance. Keywords zinc ferrite-based; coprecipitaion; hot gas; desulfurization 基金项目：煤气干法脱硫剂开发和实验研究(BY2011192)