P-phenylenediamine Molecular imprinted polymer Molecular Recognition Characteristics.doc

 PAGE \* MERGEFORMAT 22 P-phenylenediamine Molecular imprinted polymer Molecular Recognition Characteristics Of: Zhangtie Li Xiang-Jun Meng Jiajun Fang Han Liling [Abstract] phenylenediamine (p-PD for the template molecule, respectively, methyl methacrylate (MAA and acrylamide (AA as functional monomer was prepared by p-PD in the imprinted polymer P (MAA) and P ( AA), was investigated by chromatography of their molecular recognition properties. The results show that, P (AA) on the p-PD no obvious imprinting effect, and methanol as mobile phase, P (MAA) to selectively with p-PD molecule ( k ‘= 3.57, p-PD on a significant imprinting effect (imprinting factor IF = 2.95, P (MAA) column can achieve p-PD with o-phenylenediamine (o-PD and amino acid (p-ABA’s chromatography. by spectroscopy experiments and theoretical calculation method HF/6-31G * quantitative, comparative study of the p-PD and the interaction between MAA and AA. MAA and the p-PD to form more stable complexes, P (MAA ) on the p-PD has a better molecular recognition. studies have shown that UV absorption spectroscopy and fluorescence spectroscopy and quantum chemical calculation method can be used as an effective means of screening of functional monomers for the template molecule fluorescence, fluorescence spectroscopy is a simple, sensitivity and so on. [Keywords:] p-phenylenediamine, molecular imprinted polymers, molecular recognition, molecular spectroscopy, quantum chemistry calculation Abstract Two p-phenylenediamine (p-PD)-imprinted polymers, P (MAA) and P (AA), were synthesized using methacrylic acid (MAA) and acrylamide (AA) as functional monomer, respectively, in order to prepare molecular recognition material with high selectivity for p-PD and explore the feasibility of methods such as molecular spectrometry and computational approach of quantum chemistry for the selection of functional monomer with high imprinting efficiency.The molecular recognition properties of the imprinted po