purge and trap gas chromatography of methyl chloride and methyl bromide in seawater.doc

 PAGE \* MERGEFORMAT 13 purge and trap gas chromatography of methyl chloride and methyl bromide in seawater Study: Wang Meng Yang Guipeng Lu Xiaolan Song Guisheng [Abstract] established the seawater CH3Cl and CH3Br in the purge and trap gas chromatography method to determine the optimal experimental conditions: purge time 12 min, purge gas flow rate 50 mL / min, purge temperature of 40 ℃, the desiccant Mg (ClO4) 2, liquid nitrogen trap, boiling water, desorption 2 min. The method of CH3Cl and CH3Br in the detection limits were 2.7 and 0.3 pmol / L, the relative standard deviation of 1.9% and 7.1%, respectively, recoveries were 89 % to 97% and 75% to 85%. seawater sample storage methods on the reliability and accuracy of the site, the results show that: in the sample concentration within 24 h no significant change in the course of investigation at the scene, generally within 6 h completion can be determined, so this method can get accurate results. while the application of the method in the Jiaozhou Bay surface water samples were determined CH3Cl and CH3Br, and its concentration was 130 ~ 346 pmol / L and 3.90 ~ 20.7 pmol / L, and reported the concentration of the other coastal waters, indicating that this method can meet the sea CH3Cl and CH3Br concentration determination requirements. [Keywords:] chloride; methyl bromide; purge and trap; gas chromatography; Jiaozhou Bay 1 Introduction Methyl chloride (CH3Cl) and methyl bromide (CH3Br) is an important trace atmospheric greenhouse gases, but also the global atmospheric Cl and Br radicals in the main carrier. The two chemical reactions in the atmosphere, resulting in Cl and Br radicals, Catalytic destruction of ozone layer and atmospheric response in the other [1 ~ 3]. CH3Cl and CH3Br widespread in seawater, under natural conditions, easily through the air-sea interface into the atmosphere. oceans release or absorption of the flux of CH3Cl and CH3Br a direct impact on These two gases in the atmosph