物理化学研究方法3.pptVIP

Potential Step（Chronocoulometry);Cyclic voltammetry;Nernstian (reversible) systems;Peak current and scan rate;Totally irreversible systems;Three-electrode cell and notation for the different electrodes;;Scan rate;Differential Pulse Voltammetry/Polarography ;Differential Pulse Voltammetry/Polarography ;SMDE; ???????????????????????????????????????????????????????????? 　 ????????????????????????????????????????????????????????????;Sampled Current Polarography ;Sampled Current Polarography;Sampled Current Polarography;Potential step;Concentration profiles for various times into the experiment;Potential wave form for chronoamperometry and chronocoulometry ;Change Parameters dialog box for chronoamperometry/ chronocoulometry ;Current-time response for a double-potential step chronoamperometry experiment ;Potential step under diffusion control;Limitations imposed by Rs and Cd;Chronocoulometry;Charge-time response for a double-potential step chronocoulometry/chronoamperometry experiment ;Effects of the additional components on chronocoulometric response;Bulk electrolysis methods ; Current excitation signal for a double step chronopotentiometry experiment ;Change Parameters dialog box for chronopotentiometry;Change Parameters dialog box for double step chronopotentiometry ;Typical potential response for a chronopotentiometry experiment ;Current Step;Sand equation;Rotating disk electrode;Rotating disk electrode;Schematic resultant streamlines;Theoretical treatment of convective systems;Levich equation;The concentration profile;General current-potential curves at the RDE;Rotating ring-disk electrode;The collection efficiency;RRDE apparatus: Biopotetiostat;;理论 欧姆定律给出直流电位和直流电流的简单关系: ? E = i R (1);;+ - + - + - + - + -;+ - + - + - + - + -;;Rsol;;Bode图: lg(Z)~lg(f) 和 φ~lg(f);Spectroelectrochemistry (Ultraviolet Visible Spectroscopy); 研究物质在紫外、可见光区的分子吸收光谱的分析方法称为紫外-可见分光光度法。 紫外—可见分光光度法是利用某些物质的分子吸收200 ? 800 nm光谱区的辐射来进行分析测定的方法。这种分子吸收光谱产生于价电子