高三化学中国国家集训队上课课件3Metathesis.pptVIP

Lecture: Transition Metal Catalyzed Complexity Generating Reactions 2Metathesis;Organo-transition Metal Chemistry;Olefin Metathesis;Representative Catalysts;Developments in Catalyst;Mechanistic Model of the Metathesis Reaction;Categories of Metathesis Events;Engineering the Direction of the Equilibrium for Ring Closing Metathesis;Detailed Mechanistic Model of RCM;Factors Affecting RCM;Substitution Effects on RCM:A Comparison of Catalysts;RCM: An Invaluable Tool for Generation of Cyclic Structures in TOS;Clark. J. et al Angew. Chem. Int. Ed. 2000, 39, 372;Double RCM 2;ROM/Double RCM 1;ROM/Double RCM or RCM;ROM/RCM 2;ROM/Double RCM 3;RCM: Macrocycle Synthesis;En Masse Generation of Macrocycles Using Conformational Analysis; En Masse Generation of Macrocycles Using Conformational Analysis;Cross Metathesis 1;Cross Metathesis 2;Smith III. A. B. et al J. Am. Chem. Soc. 2000, 122, 4984 Also Furstner. A. et al Org. Lett. 2001, 3, 449;CM-RCM 2 Convergence of Intermediates to Products;Enyne Metathesis;Grubbs. R. H. et al J. Am. Chem. Soc. 1994, 116, 10802;Tandem Dienyne RCM 2;Mori. M. et al Org. Lett. 2001, 3, 1161;Enyne-CM/RCM/DA;Macro-Enyne-RCM 1  Type II Diene Formation;Macro-Enyne-RCM 2 Transannular Diels-Alder Reaction;Diyne Metathesis;Diyne Macro-RCM;Tandem AA and RO-RCM ;RCM-Heck Reaction;Tandem Heck-RCM;Combination of Enyne-RCM with Intermolecular Diels-Alder Reaction