煤H20气化中含氮气相产物释放规律研究.pdfVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：094186 煤-H 0 气化中含氮气相产物释放规律研究 2 翁青松，林俊光，刘银河，刘艳华，车得福 西安交通大学动力工程多相流国家重点实验室，西安 710049 (Tel: 02982663944, Email:wqs1205@126.com) 摘要 在煤水蒸气气化实验反应系统上对神木煤水蒸气气化过程中燃料氮向气相含氮产物的转化规律 和影响因素进行了实验研究。结果表明，HCN 、NH3 和N2 是煤水蒸气气化过程中主要气相含氮产物。 水蒸气是煤水蒸气气化中含氢基团的主要来源，既作为气化剂参与气化反应，也起着活化反应的作用。 随着温度不断升高， HCN 和NH3 的转化率增加，但N2 的转化率随着温度的升高先增大后减少。随着 水蒸气体积分数的增大，HCN 、NH3 和N2 收率均先增大后减小，其中NH3 和N2 的变化趋势尤为明显。 NH3 和HCN 收率随着气流速率的增加先是基本保持不变，而后出现持续下降。 关键词 煤；气化；HCN ；NH3 ；N2 Release of Gaseous Nitrogenous Products during Coal Gasification in Steam WENG Qing-Song, LIN Jun-Guang, LIU Yin-He, LIU Yan-Hua, CHE De-Fu (State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049, China) Abstract The conversion of fuel nitrogen to gaseous nitrogenous products during coal gasification in steam was investigated in the reactor. The results show that the major gaseous nitrogenous products include HCN, NH and N . H O is the main source of groups containing hydrogen, which not only participates the reaction 3 2 2 as a gasification agent, but also has activation effect on the reaction. HCN and NH3 increase with increased temperature, while the yeild of N2 increases firstly and then decreases with increased temperature. The yeilds of HCN, NH and N increases firstly and then decreases with increased temperature respectively, especially 3 2 the trend of NH and N . The yeilds of HCN and NH keep almost unchanged firstly and then decreases with 3 2 3 increased gas flow rate. Keywords coal; gasification; HCN; NH ; N 3 2 0 前言 随着环境问题的日益突出，煤的高效、清洁利用已经成为迫切需要解决的问题，所 以煤气化技术正成为