COMPARISON OF RUTHENIUM CATALYSTS SUPPORTED ON BETA AND MORDENITE IN THE HYDROCYCLOALKYLATION OF BENZENE.docVIP

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COMPARISON OF RUTHENIUM CATALYSTS SUPPORTED ON BETA AND MORDENITE IN THE HYDROCYCLOALKYLATION OF BENZENE.doc

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COMPARISON OF RUTHENIUM CATALYSTS SUPPORTED ON BETA AND MORDENITE IN THE HYDROCYCLOALKYLATION OF BENZENE

Petroleum Coal ISSN 1337-7027 Available online at www.vurup.sk/pc Petroleum Coal 50 (1), 44-51, 2008 COMPARISONOFRUTHENIUMCATALYSTSSUPPORTEDON BETA ANDMORDENITEINTHEHYDROCYCLOALKYLATIONOFBENZENE Milan Kralik*, Zuzana Vallusova , Jan Laluch , Jozef Mikulec , Vendelin Macho3 1 1 2 Research Institute of Chemical Technology, Nobelova 34, 836 03 Bratislava, c/o 1Institute of Organic Chemistry, Catalysis and Petrochemistry, Slovak Technical University, Radlinskeho 9, 812 37 Bratislava 1, Slovak Republic 2Slovnaft VURUP, a.s., Vlcie hrdlo, 842 12 Bratislava 23, Slovak Republic 3Department of Chemistry and Technology of Polymers, Faculty of Industrial Technologies, Alexander Dubcek University in Trencin, I. Krasku, 491/30, 020 01Puchov, Slovak Republic Received August 30, 2007, accepted March 15, 2008 Abstract One way of conversion of benzene into a valuable component of motor fuel is hydrocycloalkylation producing cyclohexylbenzene (CHB) and dicyclohexylbenzene (DCHB). Two catalysts containing 0.2 wt. % of ruthenium were prepared using mordenite (Ru/M) and beta (Ru/B) zeolites as supports. Catalytic tests were carried out in a batch o reactor at 175 and 200 C and hydrogen pressure of 2 MPa at maximum. Cyclohexane was used as a solvent. Better results were obtained with Ru/B catalyst, which corresponds with better accessibility of the interior space. Selectivity to sum of CHB and DCHB varied from 60 down to 40 % at the conversion of benzene 30 and 80 %. Obtained results should motivate further technological investigation of the process. Key words: hydrocycloalkylation;benzene; cyclohexylbenzene; dicyclohexylbenzene; beta-zeolite; ruthenium; motor fuel 1. Introduction Due to increasingly stringent legislation, content of aromatics, particularly benzene, which is a proven human carcinogen [1], has started to be strongly limited in motor fuels. The current EU legislation valid from 2005 prescribes the content of benzene