分离、富集液相中金离子的反应型材料.PDFVIP

《化学通报》在线预览版 分离、富集液相中金离子的反应型材料 1 2 1 赵可江 ，赵亮 ，王新军 1 河南师范大学化学与环境科学学院，新乡 453007 2 河南省科学院化学研究所，郑州 450002 摘要 本文介绍了近些年来国内外以化学吸附纤维（离子交换和螯合纤维）、活性炭纤维和树脂等有机功能材料为基础研 究开发分离、富集液相中金离子（Au3+和 Au+ ）的研究进展，其中包括含N 、O、S 等各种官能团有机功能纤维和树脂、 活性炭纤维对液相中金离子吸附的实验理论研究、预富集分析测试和实际湿法冶金中的应用，对于不同吸附材料对金离 子的吸附行为、吸附机理、影响因素等进行了初步探讨。指出了反应型材料的优势和目前所存在的问题，对其应用前景 作了适当展望。 关键词：化学吸附纤维 离子交换和螯合纤维 活性炭纤维 树脂 金离子 Advance of Reactive Material for the Separation and Enrichment of Au Ion in the Liquid Phase 1 2 1 Zhao kejiang , Zhao Liang ，Wang Xinjun 1The College of Chemistry and Environment Science,Henan Normal University,XinXiang 453007 2The Institute of Chemistry Henan Academy of Sciences,ZhengZhou 450002 + 3+ Abstract It is introduced in this article the advance of the separation and enrichment of Au ion(Au ,Au ) from liquid phase on the basis of reactive material(chemical adsorptive fiber(ion exchange and chelating fiber),active carbon fiber(ACF),resin et al) in China and abroad in recent years,which includes the experimental theoretical research,pre-enrichment analytical test and application in hydrometallagy by organic functional fiber and resin with functional groups containing N,O,S atom,ACF.As for different adsorbents,it simply discusses the gold adsorption performance,adsorption mechanism,affecting factor.Last it points out the advantages and the defects of the reactive material,and properly forcasts its application prospects. Key words Chemical Adsorptive Fiber, Ion Exchange and Chelating Fiber, Active Carbon Fiber, Resin, Au I