第二章之电化学阻抗谱及其应用.pptVIP

* 第三步：利用专业的EIS分析软件，对EIS进行曲线拟合。如果拟合的很好，比如这个图红色是测量的，绿色是拟合结果， 那么就说明这个等效电路有可能是该系统的等效电路。 * 最后，利用拟合软件，可得到体系R?、Rct、Cd以及其他参数， 再利用电化学知识赋予这些等效电路元件以一定的电化学含义，并计算动力学参数。 必须注意的是：电化学阻抗谱和等效电路之间不存在唯一对应关系，也就是说，同一个EIS往往可以用多个等效电路来很好的拟合。至于具体选择哪一种等效电路，就要考虑等效电路在具体的被侧体系中是否有明确的物理意义，能否合理解释物理过程。这是等效电路曲线拟合分析法的缺点。但是这种方法比较简单，所以目前大都采用这种方法。其他的分析方法较复杂，使用的不是很普遍，我们就不做介绍了。 * 本门课程到此结束，感谢同学们的合作，预祝大家考个好成绩。 * * * 电化学工作站： * 测试接线方式： Green – Working (WE) electrode lead. This lead connects to the electrode of interest at which the desired reactions will occur. The current (I) is measured through the WE. Red – Counter (CE) electrode lead. This lead connects to the electrode opposite the WE and controls the power output of the VersaSTAT 3F. Gray – Sense (SE) electrode lead. This usually connects to the working electrode (the combination often referred to as the working-sense), and is a component of the differential amplifier that measures/controls the voltage between itself and the reference electrode. White – Reference (RE) electrode lead. This connects to the reference electrode, a component of the differential amplifier that measures/controls the voltage between itself and the sense electrode. Black – Ground lead. The use of the ground lead depends on the application, but it is not ordinarily used in most experiments. It can be used to supply a ground point to a Faraday shield for the experimental cell, and is used in some open circuit experiments to form a zero-resistance ammeter (ZRA). * a) Batteries, capacitors, resistors, fuel cells, and some sensors are generally connected using a two-terminal connection (Figure 6). The connectors for the cable leads are designed to allow easy interconnection of the working/sense and reference/counter leads. Note: If your cell has low impedance (battery) and/or your experiment generates currents in excess of 100mA, do not connect the leads into one another for a two-terminal connection. Instead, connect the leads independent of one another to their proper termin