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HeatTreatmentofSteel-CaliforniaStateUniversity
HEAT TREATMENT OF STEEL
Background Unit: Heat Treatment of Steel
Introduction
Figure 1 shows a slightly simplified version of the Fe- Fe C alloy system. (The simplification
3
consists of ignoring complex freezing behavior between 0% C and 0.53% C and between 1394°C and
1538°C. This behavior arises from the formation of δ, delta, the high-temperature body centered cubic
form of iron, which is ignored here. Since all steels will pass through the single-phase austenite (γ,
gamma) region and the heat treatment of steel is concerned with the conversion of γ to other phases at
lower temperature, ignoring the δ-iron isn’t too serious. Four phases occur on the diagram in Fig. 1:
1. liquid, L, by itself at all temperatures above the liquidus, and mixed with a solid phase at
temperatures between the liquidus and solidus.
2. austenite, γ, the solid solution of carbon with FCC γ iron.
3. ferrite, α., the solid solution of carbon with BCC a iron.
4. cementite, Fe C, or iron carbide, a compound of iron and carbon.
3
Notice that austenite can dissolve much more carbon than ferrite. Especially notice that at 727oC
the ferrite can dissolve only 0.02% C while the austenite can dissolve 0.77% C.
The Fe-Fe3C phase diagram is the basis of steels and cast irons. Plain carbon steels contain up to 2.11%
C and cast irons contain more than 2.11% C.
Figure 1 – Iron – Iron Carbide System
Objectives
After studying this unit and completing the lab assignment you should be able to complete the
following tasks:
1. Write complete definitions of the following terms:
a. austenite e. hardening, or quenching
b. ferrite f. tempering, or drawing
c. cementite g. plain carbon steel
d. martensite h. eutectoid reaction
2. Given the Fe-Fe3C phase dia
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