水环境中不容忽视的磷形态—低价磷酸盐.docVIP

Sustainable Development 可持续发展, 2011, 1, 59-64 /10.12677/sd.2011.12010 Published Online July 2011 (/journal/sd/) The Non-negligible Phosphorus Form—Reduced Phosphorus in Water# Hongjun Wang, Ruixiang Cao, Juan Zhang, Chao Han, Xueyuan Gu, Jinju Geng , * Xiaorong Wang, Xin Qian State Key Laboratory of Pollution Control and Resources Reuse, School of Environment, Nanjing University, Nanjing Email: wanghongjun2258@126.com; jjgeng@ Received: May 6th, 2011; revised: Jun. 17th, 2011; accepted: Jun. 28th, 2011. Abstract: Reduced phosphorus compounds, such as phosphite ( H PO3 ? and HPO32? ,+3), hypophosphite 2 ( H PO2 ,+1), and phosphine (PH ,–3), have long been neglected in the phosphorus geochemical cycle. Re- ? 3 2 cently reduced phosphorus compounds have been detected in many environmental sites. Their role in the phosphorus cycle is becoming a hot study spot. However, their complex environmental behavior makes a headache for many researchers due to such characteristics as the specific chemical characteristics, such as the thermo dynamical instability, kinetic stability and vast water-solubility, of the reduced phosphorus com- pounds induce their complicated environmental behavior and fate. This paper reviewed the sources and dis- tribution, migration and transformation, and bioavailability of reduced phosphorus compounds in aquatic wa- ter environment. Also, analytical methods of reduced phosphorus compounds in aquatic environment were systematically expatiated. The work is helpful to further study the biogeochemical mechanisms of phosphorus in eutrophic lakes, reveal the environmental behavior of reduced phosphorus, and provide scientific informa- tion for policymakers to make a better decision on eutrophication control. Keywords: Aquatic Environment; Phosphorus Cycle; Reduced Phosphorus Compounds; Environmental Behavior 水环境中不容忽视的磷形态——低价磷酸盐# * 王红军，曹瑞香，张 娟，韩 污染控制与资源化研究国家重点实验室，南京大学环境学院，南京 超，顾雪元，耿金菊，王晓蓉，钱