添加剂对钛精矿固相碳热还原强化作用的比较.pdfVIP

第34 卷第11 期 东北大学学报(自然科学版) Vo l. 34 ,No. 11 2013 年 11 月 Joumal of Northeastem University( Natura1 Science) Nov. 2013 添加剂对铁精矿固相碳热还原强化作用的比较 吕学伟，张凯，黄润，宋兵 (重庆大学材料科学与工程学院，重庆 40∞44) 摘 要:利用热重分析法研究了硅铁、棚砂、碳酸铀三种不同添加剂对钦精矿固相碳热还原行为的影响 对这三种添加剂的 TG， DTG， DSC 曲线进行分析，结果表明硅铁会使钦精矿在还原过程中的失重率减少;而 碳酸铀和棚砂会使铁精矿在还原过程中的失重率增加三种添加剂都可以使达到最大反应速率时的温度降 低.碳酸锅和珊砂可以显著提高其最大反应速率，分别提高了 0.13% /min 和0.18% /min; 硅铁使最大反应速 率降低.其强化还原机理为硅铁为反应提供一定热量，提高了反应体系的温度;棚砂促进还原过程中反应物的 传输;碳酸铀可以增强碳的气化反应. 关键词:铁精矿;添加剂;固相还原;热重法;失重率 中图分类号: TF 533.2+7 文章编号: 1005 -3026(2013)11-1601-05 文献标志码:A Comparison of the Effecû写 of Different Additives on the Solid Phase Carbon Thermal Reduction of Ilmenite LYU Xue-wei , ZHANG Kα， i ， HUANG Run , SONG Bing ( College of Materials Science and Engineering , Chongqing University , Chongqing 4仪泊44 ， China. Corresponding author; LYU Xue-wei , E-m缸1; 1vxuewei@ cqu. edu. cn) Abstract: 白le effects of adding Fe-Si , Na B 0 , Na C0 on the solid phase reduction behaviors 2 4 7 2 3 of ilmenite were studied with the thermogravimetric ana1ysis (TG). From the ana1ysis of the TG , DTG and DSC curves , the results showed 出at the mass 10ss ratio of the mixture of the ilmemite and coke during the reduction decreased by adding Fe-Si , while increased by adding Na C0 or 2 3 Na B 0 • All the three additives reduced the temperature at which the maximum reaction rate was 2 4 7 obtained. The maximum mass loss rates of the reduction pro