乙烯四聚催化体系双膦胺配体的结构与性能.pdfVIP

学兔兔 化 工 进 展 2011年第 30卷第5期 CHEMICAL INDUSTRY AND ENGINEERIN G PROGRESS ·1003· e e ≈ 《进展与述评 气 乙烯四聚催化体系双膦胺配体的结构与性能 宁英男，薛秋梅，毛国梁，姜 涛 (东北石油大学化学化工学院，黑龙江 大庆 163318) 摘 要：简述了乙烯四聚反应制备 1一辛烯催化体系的最新研究进展。指出乙烯四聚制l-辛烯催化体系中配体的结 构和电子性是影响催化体系的活性和目的产物1一辛烯的选择性的主要因素。PNP配体中N取代基和P取代基的 空间位阻和给电子效应都会对催化体系的活性和 1一辛烯选择性产生影响。分析了由于取代基空间体积的增大和 电负性的增强均使乙烯的进一步插入受阻，因而降低了催化体系的活性和 l一辛烯的选择性。表明了设计合成新 型的配体对提高催化体系活性和1一辛烯选择性至关重要。 关键词：乙烯四聚；1-辛烯；双膦胺配体；结构与性能 中图分类号：TQ426 文献标志码：A 文章编号：1000—6613(2011)05—1003—05 Structures and properties of diphosphinoamine ligands in ethylene tetramerization catalyst system NING Yingnan，XUE Qiumei，MAO Guoliang，JIANG Tao (School of Chemis~yChemical Engineering，Northeastern Petroleum University， Daqing 163318，Heilongjiang，China) Abstract：Recently progress of the catalytic system for ethylene tetramerization toward 1一octene is summarized．The structure and electronic property of PNP ligand are the mainly factors affecting the catalytic activity and the selectivity of the catalytic system．The bulk and electronic properties of N-substituented and P—substituented groups in PNP ligand have important effect on catalytic activity and selectivity to 1一octene．The substituent with bulkier and richer electronegatiVity will result in hindering further ethylene insertion，which induces lower catalytic activity and lower selectivity to 1一octene．The design and synthesis of a novel ligand is crucial to higher catalytic activity and higher selectivity to 1一octene． Key words： ethylene tetramerization； l—octene； bis【diphen