含NaCl_KCl葡萄糖水溶液的密度和粘度测定及分析.pdfVIP

Vol . 29 No. 2 2003-04 Journ al of East Chin a University of Science an d T echnolo y 129 : 1006-3080( 2003) 02-0129-05 NaCl KCl * 赵长伟 , 　马沛生, 　华　超 ( 天津大学化工学院, 天津300072) : 在 = 0. 05、0. 10、0. 15、0. 20、0. 25 的葡萄糖水溶液中加入 、 , 在 293. 15 ～ w NaCl KCl K 323. 15K 下测 了该溶液的密度及粘度。回归计算了NaCl、KCl 在该体系中的密度参数及粘度B 系数。结果表明, 在葡萄糖含量及NaCl、KCl 浓度一 的情况下, 体系的密度和粘度随温度升高而 减小; 在同一温度及 、 浓度下, 随葡萄糖含量的增加体系的密度和粘度随之增加; 两种电 NaCl KCl 解质的 系数随葡萄糖含量的增加及温度的升高也增大; 在此基础上进 一步讨论了该体系内部溶 B 质-溶剂、溶质-溶质间的相互作用, 说明了NaCl、KCl 对葡萄糖水溶液的结构会有 一 的促进和破 坏作用。 : 葡萄糖; 密度; 粘度; 氯化钠; 氯化钾 : T Q0 13. 1 : A Measurement and Analysis of Densities and Viscosities of Aqueous Glucose Solutions with NaCl and KCl - * , - , ZH A O Chang w e i M A Pe i sheng H UA Chao ( S chool of Chemical Eng ineer ing and Technology , T ianj in Univ er si y , Tianj in 300072, Ch ina) Abstract: Viscosities and densities of aqueous lucose solution w ith different concentrations of NaCl 293. 15 323. 15 . and KCl fr om K to K are reported T he parameters of densities and viscosity B coefficients have been calculated by r e ression. T he experimental results show that densities and viscosities decrease w ith the increasin of temperatur e at the same concentrations of NaCl, KCl and lucose, and increase w ith the increasin of concentration of lucose at the same temperature and the same concentrations of NaCl and . . , KCl B coefficients i