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Chapter 4
Signal Characteristics
The great mystery of the spin echo was what made the spins
get back in phase again? Was echo a challenge to the basic
concepts of irreversibility? Was there a Maxwell demon at
work producing the refocusing?
Charles P. Slichter
In this chapter, we examine in detail time signals observed from a nuclear spin
system after pulse excitations. We classify these signals into three major cate-
gories: free induction decays (FID), RF echoes, and gradient echoes. For each
type of signal, we describe its excitation requirements, general characteristics,
and mathematical expression.
4.1 Basic Assumptions
Let us state some general assumptions underlying the discussion throughout this
chapter.
First, we assume that an RF pulse is applied instantaneously so that the pulse
interval is treated as zero. If precise timing of the occurrence of a signal is desired,
finite pulse intervals need to be properly accounted for, but this is rarely the case
in practice.
Second, we ignore any imperfections in excitation and reception so that any
phase shift due to off-resonance effects and nonuniform B; weighting on the re-
ceived signal are omitted. Under this assumption, we can use the simplified signal
expression in Eq. (3.150). Furthermore, for notational convenience, we will re-
place dw by w so that w now represents the precessional frequency in the rotating
107
108 Chapter 4 Signal Characteristics
frame. Consequently, Eq. (3.150) can be written as
S(t) = f M,y(r,O+)e-t/T2(r)e-iw(r)tdr
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