CHE1316LaboratoryMeasurementsTechniques.pptVIP

CHE 1316 Laboratory Measurements Techniques Metal Ion Complexation Formation Constants Polydentate Ligands Complexation Involving EDTA Formation Constants KMY Complexation Involving EDTA Effect of pH on Titrations Effect of KMY on Titrations EDTA Titrations Suggested Problems Problem Set 8 (lab manual) 1-8 * LECTURE 9 Complexation Complexometric Titrations /chemistry Mn+ + x Lm? MLxn?xm metal ligand complex If m = 0, then (n?xm) = n+ If m ? 0, then (n?xm) = +, ?, or 0 Cu2+ + 4 NH3 Cu(NH3)42+ Cu2+ + 2 NH2CH2COO? Cu(NH2CH2COO)2 Cu2+ + 4 Cl? Cu(Cl)42? Bond = Coordinate Covalent Bond (