微球负载TiO2催化剂的制备与降解苯酚性能.pdfVIP

维普资讯 学兔兔 化 T 进 展 2008年第27卷第4期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·577· 微球负载TiO2催化剂的制备与降解苯酚性能 张乐观，朱新锋 (平顶山工学院环境工程系，河南 半顶}lJ 467001) 摘 要：以粉煤灰中分离的微珠为载体，采用溶胶一凝胶法制备了负载型TiO2光催化剂，通过XRD、SEM技术对 粉煤灰微珠负载TiO，光催化剂的晶型结构和形貌进行了表征；采用悬浮体系以苯酚为降解对象，研究了TiO2光 催化活性。结果表明：负载TiO2催化剂在悬浮体系中具有较高的光催化活性，催化剂负载4次，500℃煅烧2h， 降解苯酚的能力最强，在苯酚浓度为102mg／L，120min降解率达到60％。 关键词：粉煤灰微球；二氧化钛；光催化；苯酚 中图分类号：O 625．32 文献标识码：A 文章编号：1000—6613(2008)04—0577—04 Preparation of nano-sized TiO2 immobilized on fly ash microsphere and photocatalytic degradation of phenol ZHANGLeguan，ZHUXinfeng (Department ofEnvironment Engineering，Pingdingshan Institute ofTechnology，Pingdingshan 467001，Henan，China) Abstract：TiO2 loaded photocatalysts immobifized on ny ash micro—sphere were prepared by the sol—gel methods．The crystal phase and morphology of TiO2／microsphere were investigated with XRD and SEM． Th e photocatalytic activities of TiO2／mi crosphere with different preparation conditions and TiO2 amounts on micro—sphere were evaluated by degradation of pheno1．Th e results showed the best conditions of preparation as follows：four times of catalyst loading，calcination at 550℃ centigrade for 2 hours．When phenol concentration was 102 mg／L，degeneration rate reached 60％ after 120 mi nutes． Key words：fly ash microsphere：titanium oxide；photocatalyst；phenol 半导体光催化由于能在常温常压下使多种类型 下溶于无水乙醇中，加入一定量三乙醇胺和可溶 的难降解有机物催化分解为二氧化碳和水，不会造成 性淀粉，混合搅拌一段时间后，逐滴滴加无水乙 二次污染而越来越引起国内外科研人员的重视，特别 醇和蒸馏水的混合液，制备成淡黄色的透明溶胶。 是在环境保护方面的突出优点，