载体酸处理对蓄热-催化双功能催化剂性能的影响.pdfVIP

学兔兔 化 工 进 展 ·2164· CHEMICAL 1NDUSTRY AND ENGINEERING PROGRESS 2009年第28卷第l2期 载体酸处理对蓄热．催化双功能催化剂性能的影响 王 静，徐 丽，付名利，黄碧纯，叶代启 (华南理工大学环境科学与工程学院，广东 广州 510006) 摘 要：研究了载体硝酸处理对自制蓄热一催化双功能催化剂性能的影响。利用DSC和XRD等手段对其进行了表 征，采用表面吸附仪测定了催化剂的N2吸附脱附等温线，并由BET理论模型计算其比表面积，考察了催化剂在 实验室规族流向变换反应器中的应用特性。结果表明，酸处理并未改变载体的物相结构，对催化剂的蓄热性能几 乎无影响；载体经硝酸处理后，催化剂催化活性增强，稳态操作中甲苯转化率在400℃时为97．42％，比酸处理前 提高了近5％；酸处理后，催化剂在流向变换反应器应用中亦表现出良好的蓄热性能。 关键词：酸处理；蓄热；催化剂 中图分类号：TQ 032 文献标识码：A 文章编号：1000—6613(2009)12—2164—05 Acid treatment of support on the performance of catalysts combined with heat storage function WANGJing，XULi，FUMingli，HUANGBichun，YEDaiqi (College ofEnvironmental Science and Engineering，South China University ofTechnology，Guangzhou 510006， Guangdong，China) Abstract：The effect of support treatment with HNO1 on the performance of the self-made catalysts combined with heat storage function was studied．The catalysts were characterized bv DSC and XRD techniques，and the specific surface area were calculated using BET theoretical models according to their nitrogen adsorption isotherms．Besides，the application characteristics of the catalysts combined with heat storage function in reverse flow reactor was investigated．It was found that the heat storage function of the catalysts was almost unaffected with no change in crystalline phase after acid treatment． While the catalytic activity of the catalysts was obviously enhanced after acid treatment，toluene