Co3O4／MPS催化氧化NO性能.pdfVIP

学兔兔 化 工 进 展 2009年第28卷第5期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·805· Co3O4／MPS催化氧化NO性能 高冬梅，黄 妍，童志权，张俊丰，罗 河 (湘潭大学环境工程系，湖南 湘潭411105) 摘 要：微乳法制备的介孔二氧化硅(MPS)负载co3O4构成了Co3O4／MPS催化剂，考察了负载量、焙烧温度等 制备条件和反应温度、空速、NO进口浓度、02体积分数等操作条件对Co3O4／MPS催化氧化NO性能的影响，并 对载体及催化剂进行了BET和XRD表征。结果表明：MPS比表面积远大于其它载体，co O4呈立方晶型，MPS 负载25％的Co3O4在300 oC下焙烧3 h得到催化剂的晶体颗粒最小，分散性好，具有最佳催化氧化活性和良好的 稳定性，在NO进口浓度500 L几、O2体积分数10％、空速12 000 h1的条件下，250℃时NO氧化率可达50％～ 60％(此时可获得最高的NOx吸收效率)，300℃氧化率达到80％以上，接近热力学平衡值。 关键词：Co O4／MPS催化剂；NO；催化氧化 中图分类号：x 511 文献标识码：A 文章编号：1000—6613(2009)05—0805—07 Catalytic oxidation of No over Co304／MPS GAO Dongmei，HUANG Yan，TONG Zhiquan，ZHANG Junfeng，LUO He (Department ofEnvironmental Engineering，Xiangtan University，Xiangtan 411105，Hunan，China) Abstract-The Co304／MPS catalyst was prepared by impregnating Co304 on MPS and characterized by XRD and BE MPS was prepared by the micro emulsion method．The influences of Co304 loading． calcination temperature，space velocity，reaction temperature，inlet concentration of NO and volume fraction of oxygen on the performance of catalytic oxidation were examined．The results showed that the surface area of MPS was the largest in three catalyst carriers and Co3O4 was cubic crysta1． 25％Co3O4／MPS catalyst calcined at 300℃ for 3h had the smallest crystal particles．the best surface dispersion and optimal catalytic oxidation activity． len the inlet concentration of NO was 500 LLL／L． 02 l0％，space velocity 12000 h～，the oxidation rate of NO over Co3OdMPS reached 5O％一60％at 250℃，and the highest absorption emciency was achieved．At 300℃，the oxidation rate wa