SiO2催化苯酚与碳酸二乙酯邻位烷基化反应.pdfVIP

学兔兔 化 工 进 展 2011年第3O卷第5期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS l／ e 《研究开发； 奇 Cr2O3／SiO2催化苯酚与碳酸二乙酯邻位烷基化反应 贾 泉，薛 冰，许 杰，李永昕 (常州大学石油化工学院，江苏 常州 213164) 摘 要：以Cr(NO3)39H2O为前体，采用等体积浸渍法制备了一系列不同Cr2O3负载量的cr2O3／SiO2催化剂；在 固定床连续微反装置上，考察了Cr2O ／SiO2催化剂对苯酚与碳酸二乙酯邻位烷基化反应的催化性能；采用XRD、 NH 一TPD、CO 一TPD和吡啶吸附、红外等手段对催化剂进行了表征。实验结果表明，随着Cr203负载量的增加， 苯酚的转化率和邻乙基苯酚的选择性均逐渐增加；当cr2O3负载量达到 7．5％时，苯酚的转化率和邻乙基苯酚的 选择性均达到最大值，分别为48％和 67％。催化剂的表征结果表明，L酸中心是苯酚邻位烷基化反应的活性中 心，苯酚转化率和邻乙基苯酚选择性的变化主要是由催化剂的酸、碱中心数目变化引起的。 关键词：氧化铬／二氧化硅；碳酸二乙酯；苯酚；邻乙基苯酚；2，6一二乙基苯酚 中图分类号：TQ 243．1 文献标志码：A 文章编号：1000—6613(20l1)05～1019—05 Ortho—selective alkylation of phenol with diethyl carbonate over Cr203／SiO2 catalyst JIA Quan，XUEBing，X Jie，LIYongxin (School ofPetrochemical Technology，Changzhou University，Changzhou 213164，Jiangsu，China) Abstract：Cr203／SiO2 catalysts with different Cr203 loadings were prepared by impregnation with Cr(NO3)3。9H20 as precursor．Ortho—selective alkylation of phenol with diethyl carbonate was performed in a continuous flow fixed—bed reactor filled with Cr203／SiO2 catalysts．The Cr203／SiO2 catalysts were characterized by means of XRD，NH3一TPD，C02一TPD and FT-IR with pyridine adsorption．The results indicated that with increasing Cr203 loading，conversion of phenol and selectivity to o—ethylphenol increased；when Cr203 loading reached 7．5％，conversion of phenol and selectivity for o—ethylphenol reached a maximum of 48％ and 67％，respectively． The catalyst characterization results showed that the Lewis acid sites were the active centers of ortho—selective alkylation of ph