利用TG-MS研究NO气体在酰胺化碳纳米管吸附-脱附的性能.pdfVIP

学兔兔 化 工 进 展 2013年第32卷第5期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·1091· 利用TG．MS研究NO气体在酰胺化碳纳米管吸附一脱附的性能 金 效 齐 (文山学院生化系，云南 文山 663000) 摘 要：采用化学修饰的方法，用偶联剂 3-氨基丙基三乙氧基硅烷 (APTEs)对多壁碳纳米管进行酰胺化，并 采用红外光谱和拉曼光谱对其结构进行表征，研究结果表明，用偶联剂修饰后的碳纳米结构并未发生改变。同 时采用原位TG．MS技术研究了NO在多壁碳纳米管的吸附和脱附行为，TG等温吸附曲线结果表明，在温度一 定的条件下，酰胺化多壁碳纳米管对NO的吸附量为未改性多壁碳纳米管的3倍；TG．DTG的等温脱附曲线实验 研究表明，NO在酰胺化多壁碳纳米管脱附的温度点较多，同时其原位MS实验结果进一步印证了这一结论。另 外考察了温度对碳纳米管吸附NO性能的影响，实验结果表明吸附温度对NO在多壁碳纳米管上的吸附量有较大 的影响，酰胺化多壁碳纳米管对NO的最佳吸附温度为100℃。 关键词：多壁碳纳米管；一氧化氮；吸附；TG—MS 中图分类号：0 647；TQ 028 文献标志码：A 文章编号：1000—6613(2013)05—1091—06 DoI：10．3969~．issn．1000-6613．2013．05．022 Study on No adsorpti0n—desOrpti0n property of amide—multi·walled carbon nanotubes by TG-MS JINXiaoqi (Wenshan Normal University，Wenshan 663000，Yunnan，China) Abstract：Multi—walled carbon nanotubes(MCNTs)were modified by 3一aminopropyltriethoxysilane． The modified MCNTs were characterized by FT-IR and Raman spectra1．The results show that the structure of modified carbon nanotubes were unchanged．The mechanism of N0 adsorption—desorption of multi—walled carbon nanotubes was studied by TG—MS．The adsorption isothermal curve by TG indicated that the adsorption of capacity of amide—multiwalled carbon nanotubes are 3 times higher than that of unmodified multi．Wailed carbon nanotubes under certain temperature condition．The desorption isothermal curve by TG—DTG showed that NO desorption of modified carbon nanotubes has more temperature points．At the same time，the result of the situ MS confirillS this conclu