功能化离子液体-MDEA复配体系吸收CO_2.pdfVIP

学兔兔 化 工 进 展 · 394· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2013年第32卷第2期 功能化离子液体．MDEA复配体系吸收CO2 王占丽，徐 凡，邢小林，任保增 (郑州大学化工与能源学院，河南 郑州 450001) 摘 要：采用一步法合成了两种功能化离子液体四乙铵一丙氨酸盐([N2222][Ala])和四乙铵．丝氨酸盐([N2222][ser])， 利用IR和 H NMR对其结构进行了表征，并测定了其玻璃转化温度和分解温度；同时，在 40℃下分别将 [Nzz22][Ala]和[N2222][Ser]-~MDEA进行复配，考察复配后的体系对COz吸收性能；实验结果表明，[N2222][Ala】 和[N2222][ser]的加入对MDEA吸收CO2均有不同程度的增强作用，-3加入质量分数为10％时，体系对CO2吸收 量分别增加了8．63％和5．40％。此外，研究了20~60℃温度范围内复配体系的密度、黏度等，并比较了吸收前 后黏度的变化。 关键词：Ⅳ_甲基二乙醇胺；离子液体；二氧化碳；吸收 中图分类号：TQ 021．1 文献标志码：A 文章编号：1000—6613(2013)02—0394—06 DoI：10．3969／j．issn．1000—6613．2013．02．025 Absorption of C02 in aqueous mixtures of funetionalized ionic liquids and MDEA WANG Zhanli，XU Fan，XING Xiaolin，REN Baozeng (School ofChemical Engineering and Energy，Zhengzhou University，Zhengzhou450001，Henan，China) Abstract：Two functionalized ionic liquids(1Ls)一tetraethylammonium alaninate([N2222][Ala])and tetraethylammonium serinate([N2222][Ser])were synthesized by using the one—step method and verified with IR and H NMR，and their glass transition temperature and thermal decomposition temperature were determined．The solubility of CO2 in aqueous blends of N-methyl—diethanolamine(MDEA)and these two ILs were carried out at 40℃ and the results showed that both of these two ILs had a positive effect on the absorption of CO2，increasing by 8．63％and 5．40％，respectively,when IL’S concentration was 1 0％．Moreover，physical properties namely，density and viscosity of these mixed solutions were measured over a