孔隙发达竹质活性炭的制备及其电化学性能.pdfVIP

维普资讯 学兔兔 化 工 进 展 2008年第27卷第3期 CHEM1CAL INDUSTRY AND ENG1NEERING PROGRESS ·399· 孑L隙发达竹质活性炭的制备及其电化学性能 王玉新 ，时志强 ，周亚平 ( 天津大学理学院化学系，天津 300072； 天津大学化工学院，天津 300072) 摘 要：以毛竹废料为原料采用磷酸活化法制备了孔隙发达的活性炭，根据77 K氮气吸附等温线对其结构性质进 行了表征。以具有最高比表面积的活性炭为电极材料组装双电层电容器，测试了其充放电性质和循环伏安特性。 实验结果表明：在实验考察范围内，活化所得产品具有较高比表面积(1485~2127 m2／g)并含有大量中孔，中孔 体积为0．43～0．67 cm ／g，活性炭总孔容最高达1．53 cm。／g。以活性炭为电极材料的双电层电容器具有良好的充放 电性能和功率特性，电极比电容达197 F／g。 关键词：毛竹；活性炭；制备；电极材料 中图分类号：TQ 424．1；TM 53 文献标识码：A 文章编号：1000—6613(2008)03—0399—05 Preparation of bamboo activated carbon with high porosity and its electrochemical applications WANG Yuxin ，SHIZhiqiang2 ZHOU Yaping ， (~Department ofChemistry，School ofScience，Tianjin University，Tianjin 300072，China； School ofChemical Engineering and Technology，Tianjin University，Tianjin 300072，China) Abstract：Activated carbon with high porosity were prepared from bamboo waste with phosphoric acid activation．The structure properties of products were measured based on the N，adsorption isotherms at 77 K．Activated carbon(AC)with the highest specific surface was used to fabricate the electric double-layer capacitors(EDLCs)．And the behavior of charge／discharge and cyclic voltammetry of EDLCs was investigated．The results indicated that the activated carbon prepared under different conditions had high specific surface(1485～2127 m ／g)and considerable mesopores．The mesopore volume was 0．43—0．67 cm ／g and the highest total pore volum