弱外磁场诱导氧化沉淀法制备Fe3O4纳米粒子.pdfVIP

学兔兔 化 工 进 展 ·1410· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2009年第28卷第8期 弱外磁场诱导氧化沉淀法制备Fe3o4纳米粒子 郭 雷，胡小芳 (华南理工大学机械与汽车工程学院，广东 广州 510640) 摘 要：通过弱外磁场诱导氧化共沉淀法合成Fe304纳米粒子，并采用XRD、SEM、VMS表征产物晶型、形貌 和磁性能。结果表明，弱外磁场可诱导加速a—FeOOH向Fe3O4的相转变，产物粒子为尖晶石结构，且结晶良好； 产物粒子在外加弱磁场诱导后更倾向于向多面体形貌生长，且粒度分布变窄、粒径变大；产品的磁性能由于粒子 晶化程度、形貌、粒度分布的变化，其饱和磁化强度、矫顽力均变大。 关键词：Fe 0 纳米粒子；弱磁场诱导；氧化沉淀法；形貌 中图分类号：TG 141；TQ 110．3 文献标识码：A 文章编号：1000—6613(2009)08—1410—05 Preparation of nano-Fe304 particles induced by weak exterior magnetic field v／a oxidation precipitation GUO Lei，HUXiaofang (College ofMechannical and Automotive Engineering，South China University ofTechnology，Guangzhou 510640， Guangdong，China) Abstract：Nano—Fe304 particles were prepared by oxidative precipitation together with weak exterior magnetic field induction．The crystalline form，morphology and magnetic properties of the prepared particles were characterized by using XRD，SEM and VSM．Th e introduction of a weak magnetic field could accelerate the phase transformation of goethite fq-FeOOH)to magnetite(Fe304)．The prepared nano—Fe304 particles have a spinel structure and are well crystallized．Induced by the weak magnetic field，the particles tend to be form ed with a polyhedron morphology with a narrower particle size distribution and a larger diameter．Due to the changes in crystallinity，morphology and size distribution， the prepared nano—Fe304 particles have a higher saturation magnetization and a stronger coercive force． Key words