正辛醇为载体的乳化液膜法脱酚.pdfVIP

学兔兔 化 工 进 展 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2010年第29卷第l2期 正辛醇为载体的乳化液膜法脱酚 张海燕，庞 敏，吴 韦，罗海军，宁英男，毛国梁 (东北石油大学化学化工学院，石油与天然气化工黑龙江省重点实验室，黑龙江 大庆 163318) 摘 要：采用正辛醇为载体的乳化液膜体系进行了苯酚和邻甲酚废水的脱酚试验，研究了乳化液中的载体、表 面活性剂、内相试剂浓度和油水比对脱酚效果的影响。在传质条件方面，考察了传质搅拌速率、传质时间、乳 水比和初始酚含量等因素的影响。结果表明，在乳化液中正辛醇体积分数0．4％、油水比l：1、液体石蜡体积分 数5％、表面活性剂T154体积分数6％、内相NaOH溶液浓度为0．6mol／L、乳水比1：6的实验条件下，经过一 级乳化液膜分离过程，可快速脱除萃酚和邻甲酚，脱除平达到99％以上。 关键词：乳化液膜；废水处理；正辛醇；苯酚；邻甲酚 中图分类号：TQ028．8 文献标志码：A 文章编号：1000—6613(2010)12—2400—05 Phenol removal through emulsion liquid membrane with normal oetanol as carrier ZHANGHaiyan，PANGMin， Wei，LUOHaijun，NINGYingnan，MAOGuoliang (Provincal Key Laboratory of Oil and Gas Chemical Technology，College of Chemistry and Chemical Engineering， Northeast Petroleum University，Daqing 163318，Heilongiiang，China) Abstract：Phenol removal from wastewater containing phenol and D—cresol by emulsion fiquid membrane with normal octanol as carrier was investugated by varying oil／water ratio，carrier concentration，surfactant and internal phase reagent．Mass transfer conditions including stirring speed， mass transfer time，emulsion／water ratio and initial phenol content were also examined． Removal rate of higher than 99％was achieved through one stage of emulsion liquid membrane separation in a short time at conditions as：the concentrations of octanol，liquid wax，surfactant T 1 54，NaOH in inner phase were 0．4％，5％，6％ and 0．6 mol／L respectively，while the oil／water ratio was 1：1 and emulsion／water ratio was l：6． Key words．emulsion liquid membrane；wastewater treatment；normal octanol；phenol；O～cresol