氢能载体十氢萘制氢表观动力学.pdfVIP

学兔兔 化 工 进 展 2015年第34卷第9期 CHEMICAL INDUSTRYAND ENGINEERING PROGRESS ·3279· 氢能载体十氢萘制氢表观动力学 寇小文，顾雄毅，李平 (华东理工大学化学工程联合国家重点实验室，上海200237) 摘要：十氢萘是一种储氢密度很高的氢能载体，通过催化脱氢反应可将储存在十氢萘中的氢气释放出来。本文 考察了用于制氢的十氢萘液相脱氢反应，在Pt负载的活性炭颗粒催化剂(Pt／AC)上可获得约47％的脱氢转化率； 浓度分布显示十氢萘脱氢为分别生成萘及四氢萘的平行反应。在温度290~335~C、压力0．7～1．3MPa、搅拌转速 lO00ffmin的条件下，在间歇高压釜中考察了十氢液相催化脱氢动力学，建立了脱氢反应表观动力学模型，对十 氢萘脱氢实验数据进行非线I陛拟合，得到十氢萘脱氢表观动力学模型参数，生成萘及四氢萘的表观活化能分别 为 116．27kJ／mol、114．38kJ／mol。经统计检验，结果表明所建立的十氢萘催化脱氢表观动力学模型和参数估值是 可靠的。 关键词：Pt／AC催化剂；氢能载体；十氢萘；制氢；表观动力学 中图分类号：TQ 031．4；TQ 032．4 文献标志码：A 文章编号：1000—6613(2015)09—3279—07 DOI：10．16085~．issn．1000-6613．2015．09．011 Apparent kinetics of hydrogen production from hydrogen carrier decafin KOUXiaowen，GUXiongyi，LIPing (State Key Laboratory ofChemical Engineering，East China University of Science and Technology，Shanghai 200237， China) Abstract：Decalin，a representative liquid organic hydride，is a promising candidate for hydrogen carrier．Hydrogen stored in decalin can be released through catalytic dehydrogenation．The dehydrogenation of liquid decalin for hydrogen production was investigated，and about 47％ decalin conversion was achieved over a Pt catalyst supported on granular activated carbon．Production distribution showed that decalin dehydrogenation was a parallel reaction with the formation of naphthalene and tetralin respectively．The kinetic experiment was carried out in a high pressure autoclave，under the conditions of 290—335℃。0．7— 1．3MPa and sti~ing speed of 1000 r／min．An apparent kinetic model was used for the d