离子液体支撑液膜的研究及应用进展.pdfVIP

学兔兔 化 工 进 展 ·2092· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2009年第28卷第12期 离子液体支撑液膜的研究及应用进展 沈江南，阮慧敏，吴东柱，章 杰 (浙江工业大学化学工程与材料学院，浙江 杭州 310014) 摘 要：回顾了目前为止离子液体支撑液膜的制备方法、离子液体结构、支撑膜结构对离子液体支撑液膜稳定性 的影响因素，介绍了其在有机物分离、气体分离、分离反应耦合方面的应用。由于传统的单元操作很难满足污染 和对过程集成的要求，对离子液体支撑液膜在未来实现清洁生产的发展方向进行了展望。 关键词：离子液体；支撑液膜；膜分离；蒸汽渗透 中图分类号：TQ 028 文献标i,q~i-q：A 文章编号：1000—6613(2009)12—2092—06 Progress of supported liquid membrane with ionic liquids SHENJiangnan，RUANHuimin，WUDongzhu，ZHANGJie (College ofChemical Engineering and Materials Science，Zhejiang University ofTechnology，Hangzhou 3 10014，Zh~iang，China) Abstract：Supercritical fluids，room temperature ionic liquids，C02 expanded liquids and water，as well as their mixtures are currently regarded as green solvents．As substitution for volatile organic solvent， ionic liquids can be applied in separation process，chemical reaction，electrochemistry，and SO on．This review summarizes the recent progress in preparation method of supported liquid membrane with ionic liquids，and the effect of the structure of ionic liquids and support membrane on the stability of the supported liquid with ionic liquids．In addition，their application in organic／organic separation，gas separation，and coupling separation with reaction are also reviewed．The supported liquid membrane with ionic liquids will be one of the ways for clean production． Key words：ionic liquids；supported liquid membrane；membrane separation；vapor permeation 化工分离 (如烯烃、烷烃、芳烃的分离)以及 过选择合适的液膜和支撑材料，能够同时得到高选 天然气 (烟道气)中酸性气体的脱除是石油化工、