聚丙烯腈基活性碳纤维吸附CO_2的性能.pdfVIP

学兔兔 化 工 进 展 ·852· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2012年第3 1卷第4期 聚丙烯腈基活性碳纤维吸附CO2的性能 王 颖，张学军，马小丰，田艳红 (北京化工大学，碳纤维及功能高分子教育部重点实验室，北京 100029) 摘 要：以国产聚丙烯腈 (PAN)基碳纤维为原料，采用KOH为活化剂制备PAN基活性碳纤维。测定了不同 ACF样品的CO2吸附量，并通过氮气吸附、碘吸附以及红外光谱对所得活性碳纤维的比表面积、孔结构及表面 官能团进行表征。研究了活化温度、活化时间和表面改性对活性碳纤维 CO2吸附量的影响。结果表明，活化温 度是影响活性碳纤维CO2吸附量的主要因素。当活化温度为850℃时，所得活性碳纤维BET比表面积为 1235 m ／g，微孔比表面积为745 m2／g，在吸附温度为273 K、吸附相对压力 尸0为1时，CO2的吸附量达到87．29 mL／g。 关键词：活性碳纤维；孔结构；CO2吸附；表面改性 中图分类号：TQ 424．1 文献标志码：A 文章编号：1000～6613(2012)04—0852—05 PAN-based activated carbon fibers for C02 adsorption WANG yf ，ZHANGXuejun，MA Xiaofeng，TIAN Yanhong (Key Laboratory ofCarbon Fibers and Functional Polymers，Ministry ofEducation， Beijing University of Chemical Technology，Beijing 100029，China) Abstract：Activated carbon fibers were prepared from PAN—based carbon fiber with KOH activation． The CO2 adsorption of ACF samples was measured，and the surface area，pore structure and surface functional groups are characterized by N2 adsorption，iodine adsorption and FTIR．It shows that the activation temperature，activation time and surface modification of activated carbOn fiber affected the CO々adsorption of ACF．The results showed that the activation temperature of ACF is the major factor for CO，adsorption of ACF．When the activation temperature is 850℃，the BET surface area of ACF is 1235 m ／g，and micropore surface area is 745 m ／g．The C02 adsorption capacity ofthis sample is up to 87．29 mL／g，at the adsorption temperature of 273 K and relative pressure P 0=1． Key words：activated