聚吡咯修饰Nafion膜直接甲醇燃料电池的性能.pdfVIP

学兔兔 化 工 进 展 2012年第31卷第3期 CHEMICAL INDUSTRY AND ENG1NEERING PROGRESS ·541· 聚吡咯修饰Nation膜直接甲醇燃料电池的性能 陈胜洲，王松青，林维明 (广州大学化学化工学院，广东 广州 510006) 摘 要：用FeC1 化学氧化法制备了PPy／Nafion改性膜，采用浸渍一还原法在PPy／Nation阴极侧上沉积co金属， 制得Co—PPy／Nation电解质膜。采用TG、CV及交流阻抗谱测试了Nation膜及改性膜的热稳定性，质子电导性 和甲醇渗透性能，结果表明：PPy／Nation及Co．PPy／Nafion改性膜具有更好的热稳定性和抗甲醇渗透性。分别以 Co．PPy／Nation改性膜、PPy／Nation改性膜和纯Nation膜为电解质膜，PtRu／C为阳极催化剂，Pt／C为阴极催化剂 组装DMFC并考察其性能。实验结果表明：Co．PPy／Nation改性膜组装单电池在高浓度甲醇及大电流密度的测试 条件下，表现出更优异的电池性能。 关键词：Nation膜；聚吡咯；甲醇渗透；质子电导率 中图分类号：O 646；TM 911．4 文献标志码：A 文章编号：1000—6613(2012)03—0541—05 Studies on the performance of polypyrrole—Nation composite membranes in direct methanol fuel cells CHENShengzhou，WANG Songqing，LIN Weiming (School ofChemistry and Chemical Engineering，Guangzhou University，Guangzhou 510006，Guangdong，China) Abstract：Polypyrrole modified Naton membranes(PPy／Nafion)are prepared by FeC13 oxidation methods．In addition，Co iS chemically reduced on the cathode side of the modified membrane to prepare Co—PPy／Nation membrane．The thermal stability， methanol penetrability and proton conductivity of Nafion membranes and the modified membranes are studied by TG，CV and AC impedance．Results show that PPy／Nation and Co—PPy／Nation have better mermal stability and low methano1 permeation than Nation membrance．Membrane．electrode—assemblies(MEAs)for a DMFC are fabricated by using Nafion membranes，PPy／Nation and Co．PPy／Nation respectively，with Pt]Ru／C as an anode catalyst and Pt／C as a cathode catalyst．It iS found that the modification of Nation membrane