稻草水解液与乙腈的双水相分配特性.pdfVIP

学兔兔 化 工 进 展 ·402· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2012年第3 1卷第2期 稻草水解液与乙腈的双水相分配特性 李良智，韦 魏，芮丽莲，胡翠英，徐潇文，邱业先 (苏州科技学院化学与生物工程学院，江苏 苏州 215009) 研究了稻草水解液中的糖在乙腈．水双水相体系中的分配行为，首先重点考察了双水相的形成，分析 与稻草水解浓缩液的体积比和温度等对糖的分配系数影响。乙腈体积分数低于 50％时不能形成双水 V ：V# 等于2或者3时，在25℃下实验，上层畜含乙腈相中有葡萄糖、还原糖以及多糖同时存在， -3 V ：V# 等于3时，81．56％的葡萄糖提取到乙腈相中。在0℃下实验，上层富含乙腈相中都只检测 生物质资源；稻草；双水相系统；乙腈；糖 号：TQ 352 文献标志码：A 文章编号：1000—6613(2012)02—0402—04 Study on the partition characteristics of rice straw hydrolyzate in an acetonitrile aqueous two-phase system LILiangzhi，WEI Wei，RUILilian，HUCuiying，XUXiaowen，QIUYexian (School ofChemistry andBioengineering，SuzhouUniversity ofScience andTechnology， Suzhou 21501 1，Jiangsu，China) Abstract：Partition characteristics of straw hydrolysate in an acetonitrile—aqueous two—phase system were investigated in this paper~The formation of an aqueous two—phase system was investigated in detail．The effects of the volumetric ratio between acetonitrile and s仃aw hydrolyzate，and temperature on the distribution coemcient of sugar were studied，respectively．When the volume fraction of acetonitrile was lower than 50％，an aqueous two．phase system could not form in this study．In addition，it was observed that the glucose，reducing sugar，and polysaccharide existed in the upper phase rich in acetonitrile when the ratio of acetonitrile and straw hydrolyzate was equal to 2 or 3，and the experiments temperatu